Trinonylamine

Base Information

• Chemical Name: Trinonylamine
• CAS No.: 2044-22-6
• Molecular Formula: C27H57 N
• Molecular Weight: 395.75
• Hs Code.: 2921199090
• European Community (EC) Number: 677-576-0
• DSSTox Substance ID: DTXSID20880447
• Nikkaji Number: J97.705E
• Wikidata: Q81981535
• Mol file: 2044-22-6.mol

Synonyms:Trinonylamine;2044-22-6;N,N-di(nonyl)nonan-1-amine;tri-n-nonylamine;N,N-Dinonyl-1-nonanamine;SCHEMBL36450;1-Nonanamine, N,N-dinonyl-;DTXSID20880447;MFCD00053817;BS-21890;CS-0213234;FT-0655875;T1826;T72050

Chemical Property of Trinonylamine

Chemical Property:

• Melting Point: 35.75°C (estimate)
• Refractive Index: 1.4500 to 1.4540
• Boiling Point: 466.2°Cat760mmHg
• PKA: 9.93±0.50(Predicted)
• Flash Point: 206.9°C
• PSA: 3.24000
• Density: 0.821g/cm³
• LogP: 9.54020
• XLogP3: 12.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 24
• Exact Mass: 395.449100822
• Heavy Atom Count: 28
• Complexity: 220

Purity/Quality:

98%,99%, ^*data from raw suppliers

Trinonylamine >98.0%(T) ^*data from reagent suppliers

Safty Information:

• Statements: 34
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Nitrogen Compounds -> Amines, Aliphatic
• Canonical SMILES: CCCCCCCCCN(CCCCCCCCC)CCCCCCCCC

Technology Process of Trinonylamine

There total 4 articles about Trinonylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

oct-1-ene (111-66-0,25068-25-1) + carbon monoxide (201230-82-2) → trinonyl-amine (2044-22-6)

Guidance literature:

With ammonium hydroxide; dodecacarbonyl-triangulo-triruthenium; C₂₃H₃₂N₂O; hydrogen; In tetrahydrofuran; toluene; at 120 ℃; for 20h; under 37503.8 Torr; Reagent/catalyst; Solvent; Temperature; regioselective reaction; Autoclave; Inert atmosphere;

DOI:10.1002/cssc.201402626

Reference yield:

1-Bromononane (693-58-3) + di(n-nonyl)amine (2044-21-5) → trinonyl-amine (2044-22-6)

Guidance literature:

With ethanol; sodium carbonate; at 160 ℃;

Reference yield:

n-Nonylamin (112-20-9) → trinonyl-amine (2044-22-6)

Guidance literature:

Multi-step reaction with 2 steps

2: Na₂CO₃; ethanol / 160 °C

With ethanol; sodium carbonate;

upstream raw materials:

1-Bromononane

di(n-nonyl)amine

n-Nonylamin

oct-1-ene

Downstream raw materials:

N,N-dinonyl-N'-(phenylsulfonyl)heptanamidine

N,N-dinonyl-2-phenyl-N'-(phenylsulfonyl)acetamidine

N,N-dinonyl-N'-tosylheptanamidine

N,N-dinonyl-2-phenyl-N'-tosylacetamidine

Refernces

• 1、 Wu, Lipeng,Fleischer, Ivana,Zhang, Min,Liu, Qiang,Franke, Robert,Jackstell, Ralf,Beller, Matthias. "Using aqueous ammonia in hydroaminomethylation reactions: Ruthenium-catalyzed synthesis of tertiary amines". . p. 3260 - 3263. Retrieved 2015/03/03.