Bis(4-allyloxyphenyl)sulfone

Base Information

• Chemical Name: Bis(4-allyloxyphenyl)sulfone
• CAS No.: 41481-63-4
• Molecular Formula: C18H18O4S
• Molecular Weight: 330.405
• Hs Code.: 2909309090
• NSC Number: 85530
• DSSTox Substance ID: DTXSID70961750
• Nikkaji Number: J93.641C
• Wikidata: Q72502371
• Mol file: 41481-63-4.mol

Synonyms:41481-63-4;BIS(4-ALLYLOXYPHENYL)SULFONE;1-prop-2-enoxy-4-(4-prop-2-enoxyphenyl)sulfonylbenzene;4,4'-Sulfonylbis((allyloxy)benzene);4,4'-diallyloxy-diphenyl sulfone;bis(4-allyloxyphenyl) sulfone;NSC85530;1-Prop-2-enoxy-4-(4-prop-2-enoxyphenyl)sulfonyl-benzene;CBMicro_009221;Cambridge id 5142607;SCHEMBL536507;C18H18O4S;DTXSID70961750;JUNVYDTYJZSTKY-UHFFFAOYSA-N;4,4'-sulfonylbis(allyloxybenzene);SMSF0003727;NSC-85530;AKOS001026757;MB01290;AC-24470;BIM-0009131.P001;CS-0267375;FT-0639718;1,1'-PHENYLSULFONYL-4,4'-DIENEPROPYL ETHER;1,1'-Sulfonylbis{4-[(prop-2-en-1-yl)oxy]benzene};Z54336035

Chemical Property of Bis(4-allyloxyphenyl)sulfone

Chemical Property:

• Appearance/Colour: white powder
• Vapor Pressure: 1.15E-09mmHg at 25°C
• Melting Point: 141-142 °C(Solv: ethanol (64-17-5))
• Refractive Index: 1.559
• Boiling Point: 500.7 °C at 760 mmHg
• Flash Point: 256.6 °C
• PSA: 60.98000
• Density: 1.172 g/cm³
• LogP: 4.72980
• Storage Temp.: -20°C Freezer, Under inert atmosphere
• Solubility.: DMSO (Slightly), Methanol (Slightly)
• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 8
• Exact Mass: 330.09258022
• Heavy Atom Count: 23
• Complexity: 426

Purity/Quality:

99% ^*data from raw suppliers

bis(4-Allyloxyphenyl)sulfone ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCOC1=CC=C(C=C1)S(=O)(=O)C2=CC=C(C=C2)OCC=C
• Uses: 1,1'-Sulfonylbis[4-(prop-2-en-1-yloxy)benzene is a useful research chemical.

Technology Process of Bis(4-allyloxyphenyl)sulfone

There total 5 articles about Bis(4-allyloxyphenyl)sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

4,4'-sulfonediphenol (80-09-1,59790-00-0) + 3-chloroprop-1-ene (107-05-1) → 4,4’-sulfonylbis((allyloxy)benzene) (41481-63-4)

Guidance literature:

With potassium iodide; sodium hydroxide; In methanol; at 35 - 65 ℃; for 5h; Reagent/catalyst; Solvent;

Reference yield: 96.0%

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + 4,4'-sulfonediphenol (80-09-1,59790-00-0) → 4,4’-sulfonylbis((allyloxy)benzene) (41481-63-4)

Guidance literature:

4,4'-sulfonediphenol; With chlorine; sodium hydroxide; for 0.166667h;

propene; at 60 - 100 ℃; for 5h; Inert atmosphere; Sealed tube;

Reference yield: 94.0%

4,4'-sulfonediphenol (80-09-1,59790-00-0) + allyl bromide (106-95-6) → 4,4’-sulfonylbis((allyloxy)benzene) (41481-63-4)

Guidance literature:

4,4'-sulfonediphenol; With potassium carbonate; In acetone; for 1h; Inert atmosphere; Reflux;

allyl bromide; In acetone; Reflux; Inert atmosphere;

DOI:10.3762/bjoc.10.180

upstream raw materials:

4,4'-sulfonediphenol

allyl bromide

3-chloroprop-1-ene

propene

Downstream raw materials:

tetrabromobisphenol-S-bis-(2,3-dibromopropyl ether)

C₂₄H₃₄O₄S₅

C₃₂H₄₂O₈S₅

4,4’-sulfonylbis(2-allyl-1-(allyloxy)benzene)

Refernces

• 1、 -. "Preparation method of diallyl bisphenol S ether". Paragraph 0024-0032; 0045-0081. . Retrieved 2020/12/30.
• 2、 -. "Bisphenol-based epoxy compound using thiol-ene reaction and method for preparing the same, and composite of organic-inorganic materials comprising a cured product thereof and method for preparing the composite". Paragraph 0171-0174. . Retrieved 2017/08/24.