benzyl prop-2-en-1-yl carbonate

Base Information

• Chemical Name: benzyl prop-2-en-1-yl carbonate
• CAS No.: 22768-01-0
• Molecular Formula: C11H12 O3
• Molecular Weight: 192.214
• Mol file: 22768-01-0.mol

Synonyms:Carbonicacid, allyl benzyl ester (8CI); Carbonic acid, phenylmethyl 2-propenyl ester(9CI); Allyl benzyl carbonate; NSC 44980

Chemical Property of benzyl prop-2-en-1-yl carbonate

Chemical Property:

• Vapor Pressure: 0.0108mmHg at 25°C
• Boiling Point: 262.6°Cat760mmHg
• Flash Point: 98.6°C
• Density: 1.087g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of benzyl prop-2-en-1-yl carbonate

There total 7 articles about benzyl prop-2-en-1-yl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

carbon dioxide (124-38-9,18923-20-1) + benzyl bromide (100-39-0) + allyl alcohol (107-18-6) → allyl benzyl carbonate (22768-01-0)

Guidance literature:

With ethyl(8-diisopropylamino-3,6-dioxaoctyl)dimethylammonium bis{(trifluoromethyl)sulfonyl}azanide; at 25 ℃; for 72h; under 7500.75 Torr; Autoclave; Green chemistry;

DOI:10.1071/CH17530

Reference yield: 80.0%

allyl bromide (106-95-6) + benzyl alcohol (100-51-6,185532-71-2) → allyl benzyl carbonate (22768-01-0)

Guidance literature:

for 64h;

Reference yield: 70.0%

benzyl bromide (100-39-0) + allyl alcohol (107-18-6) → allyl benzyl carbonate (22768-01-0)

Guidance literature:

for 64h;

upstream raw materials:

Allyl chloroformate

benzyl alcohol

2-propen-1-yl 1H-imidazole-1-carboxylate

benzyl bromide

Downstream raw materials:

benzyl n-propyl carbonate

(S)-1-Phenyl-3-buten-1-ol

5,5-dimethyl-2,2-diallylcyclohexane-1,3-dione

benzyl alcohol

Refernces

• 1、 Takada, Yuki,Matsuoka, Aki,Du, Ya,Naka, Hiroshi,Saito, Susumu. "Acetals of N,N-dimethylformamides: Ambiphilic behavior in converting carbon dioxide to dialkyl carbonates". supporting information. p. 146 - 147. Retrieved 2013/04/10.
• 2、 Kamijo, Shin,Yamamoto, Yoshinori. "A bimetallic catalyst and dual role catalyst: Synthesis of N-(alkoxycarbonyl)indoles from 2-(alkynyl)phenylisocyanates". . p. 4764 - 4771. Retrieved 2007/10/03.