Bisphenol A dimethacrylate

Base Information

• Chemical Name: Bisphenol A dimethacrylate
• CAS No.: 3253-39-2
• Molecular Formula: C23H24 O4
• Molecular Weight: 364.441
• Hs Code.: 2916399090
• European Community (EC) Number: 221-846-9
• UNII: 982O8255NE
• DSSTox Substance ID: DTXSID80863135
• Nikkaji Number: J208.649B
• Wikidata: Q27116160
• Mol file: 3253-39-2.mol

Synonyms:2,2-di(4-methacryloxyphenyl)propane;Bis-DMA;bisphenol A dimethacrylate

Chemical Property of Bisphenol A dimethacrylate

Chemical Property:

• Appearance/Colour: white to slightly yellow crystalline powder
• Vapor Pressure: 5.1E-10mmHg at 25°C
• Melting Point: 72-74 °C(lit.)
• Refractive Index: 1.6000 (estimate)
• Boiling Point: 497.1°Cat760mmHg
• Flash Point: 246.4°C
• PSA: 52.60000
• Density: 1.091g/cm³
• LogP: 4.97550
• Storage Temp.: 0-6°C
• Solubility.: soluble in Methanol
• XLogP3: 6.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 8
• Exact Mass: 364.16745924
• Heavy Atom Count: 27
• Complexity: 523

Purity/Quality:

98%,99%, ^*data from raw suppliers

4,4'-Isopropylidenediphenol Dimethacrylate >98.0%(GC) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36-28

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=C)C(=O)OC1=CC=C(C=C1)C(C)(C)C2=CC=C(C=C2)OC(=O)C(=C)C
• Uses: 2,2-bis(4-Methacryloxy)phenyl)propane is used in dental restorative composite and adhesive materials.

Technology Process of Bisphenol A dimethacrylate

There total 2 articles about Bisphenol A dimethacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

BPA (80-05-7) + Methacryloyl chloride (920-46-7,26937-45-1) → 2,2-bis[4-(methacryloyloxy)phenyl]propane (3253-39-2)

Guidance literature:

In dichloromethane;

Reference yield:

→ 2,2-bis[4-(methacryloyloxy)phenyl]propane (3253-39-2)

Guidance literature:

2,2-Di-(4-hydroxyphenyl)-propan, Methacrylsaeurechlorid, in wss. NaOH, unterhalb 10grad;

Reference yield: 64.0%

2,2-bis[4-(methacryloyloxy)phenyl]propane (3253-39-2) + 2-(naphthalen-1-yl)phenylamine (92855-12-4) → 4-(2-(4-((2-((1-(2-aminophenyl)naphthalen-2-yl)methyl)acryloyl)oxy)phenyl)propan-2-yl)phenyl methacrylate

Guidance literature:

With disodium hydrogenphosphate; (S)-STRIP; palladium diacetate; silver sulfate; In toluene; at 60 ℃; for 48h; stereoselective reaction; Schlenk technique;

DOI:10.1021/acs.orglett.0c03757

upstream raw materials:

BPA

Methacryloyl chloride

Refernces

• 1、 -. "MOLECULARLY IMPRINTED SMART POLYMERS (MISPs)". . . Retrieved 2011/07/29.