(Z)-1-cyclopropylethanone oxime

Base Information

• Chemical Name: (Z)-1-cyclopropylethanone oxime
• CAS No.: 51761-72-9
• Molecular Formula: C5H9NO
• Molecular Weight: 99.1326
• Hs Code.: 2928000090
• European Community (EC) Number: 257-389-7
• Nikkaji Number: J294.895H
• Mol file: 51761-72-9.mol

Synonyms:(Z)-1-cyclopropylethanone oxime;Cyclopropylethan-1-one oxime;EINECS 257-389-7;(E)-N-(1-cyclopropylethylidene)hydroxylamine;1-Cyclopropyl-ethanone oxime;NSC 33804;AM87026

Chemical Property of (Z)-1-cyclopropylethanone oxime

Chemical Property:

• Vapor Pressure: 0.238mmHg at 25°C
• Boiling Point: 190.5°Cat760mmHg
• Flash Point: 96.3°C
• PSA: 32.59000
• Density: 1.16g/cm³
• LogP: 1.24650
• XLogP3: 0.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 99.068413911
• Heavy Atom Count: 7
• Complexity: 94.3

Purity/Quality:

99% ^*data from raw suppliers

CYCLOPROPYLMETHYLKETONE OXIME 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=NO)C1CC1
• Isomeric SMILES: C/C(=N/O)/C1CC1

Technology Process of (Z)-1-cyclopropylethanone oxime

There total 3 articles about (Z)-1-cyclopropylethanone oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

Cyclopropyl methyl ketone (765-43-5) → cyclopropyl methyl ketone oxime (51761-72-9)

Guidance literature:

Heating;

Reference yield: 52.0%

1,3-dicyclopropyl-3-phenylthio-1-butanone (140458-47-5) → cyclopropyl methyl ketone oxime (51761-72-9) + 5-phenylthio-2-pentanone oxime (140458-48-6) + diphenyldisulfane (882-33-7)

Guidance literature:

With pyridine; hydroxylamine hydrochloride; In ethanol; for 45h; Heating;

Reference yield:

Cyclopropyl methyl ketone (765-43-5) → cyclopropyl methyl ketone oxime (51761-72-9)

Guidance literature:

With methanol; potassium hydroxide; hydroxylamine hydrochloride;

upstream raw materials:

Cyclopropyl methyl ketone

1,3-dicyclopropyl-3-phenylthio-1-butanone

Downstream raw materials:

1-cyclopropylethylamine

2-cyclopropylpyrrole

1-vinyl-2-cyclopropylpyrrole

methylamine

Refernces

• 1、 Shi, Pengfei,Li, Song,Hu, Lu-Min,Wang, Cong,Loh, Teck-Peng,Hu, Xu-Hong. "The ruthenium-catalyzed C-H functionalization of enamides with isocyanates: Easy entry to pyrimidin-4-ones". supporting information. p. 11115 - 11118. Retrieved 2019/09/20.
• 2、 -. "Anthranilamide insecticides". Paragraph 0076. . Retrieved 2013/03/26.