N-Methyl-N-nitrosoformamide

Base Information

• Chemical Name: N-Methyl-N-nitrosoformamide
• CAS No.: 67809-14-7
• Molecular Formula: C2H4N2O2
• Molecular Weight: 88.0654
• NSC Number: 56382
• DSSTox Substance ID: DTXSID50218057
• Nikkaji Number: J551.632C
• Wikidata: Q83094795
• Mol file: 67809-14-7.mol

Synonyms:N-Methyl-N-nitrosoformamide;Methylnitrosoformamide;Formamide, N-methyl-N-nitroso-;67809-14-7;Nitrosomethylformamide;CCRIS 6335;BRN 1742947;NSC56382;N-nitroso-N-methylformamide;DTXSID50218057;NSC 56382;NSC-56382

Chemical Property of N-Methyl-N-nitrosoformamide

Chemical Property:

• Vapor Pressure: 46.5mmHg at 25°C
• Boiling Point: 94.9°Cat760mmHg
• Flash Point: 11.2°C
• PSA: 49.74000
• Density: 1.2g/cm³
• LogP: 0.39190
• XLogP3: -0.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 88.027277375
• Heavy Atom Count: 6
• Complexity: 62.6

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C=O)N=O

Technology Process of N-Methyl-N-nitrosoformamide

There total 1 articles about N-Methyl-N-nitrosoformamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

N-Methylformamide (123-39-7) → N-Nitroso-N-methylformamide (67809-14-7)

Guidance literature:

With cross-linked polyvinylpyrrolidone*N₂O₄; dinitrogen tetraoxide; In dichloromethane; at 20 ℃; for 2.5h;

DOI:10.1055/s-2003-40518

upstream raw materials:

N-Methylformamide

Refernces

• 1、 Celaries, Benoit,Parkanyi, Cyril. "Tin(IV) chloride-sodium nitrite as a new nitrosating agent for N-nitrosation of amines, amides and ureas under mild and heterogeneous conditions". . p. 2371 - 2375. Retrieved 2008/02/03.