Diethylenetriamine, 1,1,4,7,7-pentaethyl-

Base Information

• Chemical Name: Diethylenetriamine, 1,1,4,7,7-pentaethyl-
• CAS No.: 24426-21-9
• Molecular Formula: C14H33 N3
• Molecular Weight: 243.436
• NSC Number: 220237
• UNII: 5A64SR4ZHS
• DSSTox Substance ID: DTXSID60179185
• Nikkaji Number: J1.070.315H
• Wikidata: Q83049694
• Mol file: 24426-21-9.mol

Synonyms:1,1,4,7,7-Pentaethyldiethylenetriamine;24426-21-9;DIETHYLENETRIAMINE, 1,1,4,7,7-PENTAETHYL-;3,6,9-Triethyl-3,6,9-triazaundecane;NSC 220237;BRN 1757081;5A64SR4ZHS;NSC-220237;4-04-00-01247 (Beilstein Handbook Reference);N1-(2-(Diethylamino)ethyl)-N1,N2,N2-triethylethane-1,2-diamine;NSC220237;pentaethyldiethylenetriamine;UNII-5A64SR4ZHS;SCHEMBL2235928;DTXSID60179185;N(CC)(CCN(CC)CC)CCN(CC)CC;Bis[2-(diethylamino)ethyl]ethylamine;MFCD00015117;C14-H33-N3;LS-61896;n,n,n',n'',n''-pentaethyldiethylenetriamine

Chemical Property of Diethylenetriamine, 1,1,4,7,7-pentaethyl-

Chemical Property:

• Boiling Point: 270.6°Cat760mmHg
• Flash Point: 87.6°C
• Density: 0.865g/cm³
• XLogP3: 2.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 11
• Exact Mass: 243.267448065
• Heavy Atom Count: 17
• Complexity: 138

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCN(CC)CCN(CC)CCN(CC)CC

Technology Process of Diethylenetriamine, 1,1,4,7,7-pentaethyl-

There total 4 articles about Diethylenetriamine, 1,1,4,7,7-pentaethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

chloroethane (75-00-3) + 3-azapentane-1,5-diamine (111-40-0,98824-35-2) → N,N',N''-triethyldiethylenetriamine (105-93-1) + N,N,N',N'',N''-pentaethyldiethylenetriamine (24426-21-9) + N,N''-diethyldiethylenetriamine (4432-87-5) + N-ethyldiethylenetriamine (137554-10-0)

Guidance literature:

Further byproducts given; 1a) 4 h, 170-195 deg C, 1.0-2.1 MPa, 1b) work up and repeat of the procedure at 160-200 deg C, 6 h, 2,2 MPa;

Reference yield:

ethylamine (75-04-7,85404-22-4) + 2-(diethylamino)ethyl chloride (100-35-6) → N,N,N'-triethylethanediamine (105-04-4) + N,N,N',N'',N''-pentaethyldiethylenetriamine (24426-21-9)

Guidance literature:

With water;

Reference yield:

chloroethane (75-00-3) + 3-azapentane-1,5-diamine (111-40-0,98824-35-2) → N,N',N''-triethyldiethylenetriamine (105-93-1) + N,N,N',N''-tetraethyldiethylenetriamine (24426-20-8) + N,N,N',N'',N''-pentaethyldiethylenetriamine (24426-21-9) + N,N''-diethyldiethylenetriamine (4432-87-5)

Guidance literature:

at 190 ℃; for 7h; under 15001.2 Torr;

upstream raw materials:

ethylamine

2-(diethylamino)ethyl chloride

N,N,N',N'-Tetraethylethylenediamine

chloroethane

Refernces

• 1、 Wilson, Robert B.,Laine, Richard M.. "Transalkylation Reaction. Homogeneous Catalytic Formation of C-N Bonds". . p. 361 - 369. Retrieved 2007/10/02.