Phosphinic acid, (o-bromophenyl)phenyl-

Base Information

• Chemical Name: Phosphinic acid, (o-bromophenyl)phenyl-
• CAS No.: 109817-40-5
• Molecular Formula: C12H10 Br O2 P
• Molecular Weight: 297.088
• DSSTox Substance ID: DTXSID70149056
• Nikkaji Number: J3.099.556B
• Wikidata: Q83014735
• Mol file: 109817-40-5.mol

Synonyms:(o-Bromophenyl)phenylphosphinic acid;Phosphinic acid, (o-bromophenyl)phenyl-;BRN 3285221;109817-40-5;4-16-00-01049 (Beilstein Handbook Reference);C12H10BrO2P;C12-H10-Br-O2-P;DTXSID70149056;Phenyl 2-bromophenylphosphinic acid;LS-106138

Chemical Property of Phosphinic acid, (o-bromophenyl)phenyl-

Chemical Property:

• Vapor Pressure: 1.34E-10mmHg at 25°C
• Boiling Point: 494.6°Cat760mmHg
• Flash Point: 252.9°C
• Density: 1.58g/cm³
• XLogP3: 2.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 295.96018
• Heavy Atom Count: 16
• Complexity: 276

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(=O)(C2=CC=CC=C2Br)O

Technology Process of Phosphinic acid, (o-bromophenyl)phenyl-

There total 2 articles about Phosphinic acid, (o-bromophenyl)phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diphenyl-phosphinic acid (1707-03-5) → (2-bromo-phenyl)-phenyl-phosphinic acid (109817-40-5)

Guidance literature:

diphenyl-phosphinic acid; With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; hexane; at 20 ℃; for 2h; Inert atmosphere;

With benzyl bromide; In tetrahydrofuran; hexane; at 20 ℃; for 2h; Inert atmosphere;

With hydrogenchloride; In tetrahydrofuran; hexane; water; Inert atmosphere;

DOI:10.1016/j.tet.2012.06.088

Reference yield:

→ (2-bromo-phenyl)-phenyl-phosphinic acid (109817-40-5)

Guidance literature:

/BRN= 3380084/;

DOI:10.1021/ja01131a048

Reference yield:

methanol (67-56-1) + (2-bromo-phenyl)-phenyl-phosphinic acid (109817-40-5) → (2-bromo-phenyl)-phenyl-phosphinic acid methyl ester

Guidance literature:

With phosphorus pentachloride;

DOI:10.1021/ja01102a033

upstream raw materials:

diphenyl-phosphinic acid

Refernces