perrhenate

Base Information

• Chemical Name: perrhenate
• CAS No.: 14333-24-5
• Molecular Formula: O₄Re
• Molecular Weight: 249.998
• Mol file: 14333-24-5.mol

Synonyms:Perrhenate(ReO41-) (8CI); Perrhenate; Perrhenate (ReO4-); Perrhenate ion (ReO41-);Rhenate (ReO4-); Rhenate (ReO41-); Tetraoxorhenate(1-)

Chemical Property of perrhenate

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 50.75000
• Density: g/cm³
• LogP: -0.36970

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of perrhenate

There total 46 articles about perrhenate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

bis(1,2-dihydroxybenzene)dioxorhenium(VII) → bis(1,2-dihydroxybenzene)oxorhenium(V) (129869-52-9) + perrhenate (14333-24-5)

Guidance literature:

In benzyl alcohol; byproducts: PhCHO; N2, at room temp.; UV, NMR;

DOI:10.1002/ejic.201101044

Reference yield: 60.0%

rhenium → perrhenate ion (14333-24-5)

Guidance literature:

In water; nitric acid; aq. HNO3; other Radiation; 5 mg of irradiated metal powder dissolved in 2 ml of 6M HNO3, 5 ml of H2O added and evapd. at 120°C by using C2Cl4 as heat medium, addingand evapn. repeated 5 times; dissolved in 10 ml of H2O; thin-layer chromy.; ion chromy.;

Reference yield:

ReO4*2H(1+)*OCCO2(CH2CO2)2(4-) = [ReO4*H2OCCO2(CH2CO2)2](2-) → perrhenate (14333-24-5) + citric acid (77-92-9,906507-37-7)

Guidance literature:

With potassium chloride; In water; 3°C; Kinetics;

DOI:10.1021/ic50224a037

upstream raw materials:

hexabromorhenate(VI)^(2-)

water

oxygen

hexachlororhenate(VI)^(2-)

Downstream raw materials:

[ReOCl₂(HC(3,5-Ph₂-pyrazole)2CO₂)]

Na⁽¹⁺⁾*C₂B₉H₁₀C₆H₅Re(CO)3^(1-)=NaC₂B₉H₁₀C₆H₅Re(CO)3

(C₆H₅)3PN⁽¹⁸⁸⁾ReO₃

Refernces

• 1、 Vajo,Aikens,Ashley,Poeltl,Bailey,Clark,Bunce. "Facile electroreduction of perrhenate in weakly acidic citrate and oxalate media". . p. 3328 - 3333. Retrieved 1981.
• 2、 Herrmann, Wolfgang A.,Geisberger, Martin R.,Kühn, Fritz E.,Artus, Georg R. J.,Herdtweck, Eberhardt. "Syntheses of metal carbonyls. 23: Crystal structure and reactivity of heptamethylindenyl carbonyl metal complexes". . p. 1229 - 1236. Retrieved 1997.
• 3、 Marchi, Andrea,Duatti, Adriano,Rossi, Roberto,Magon, Luciano,Mazzi, Ulderico,Pasquetto, Antonio. "". . p. 15 - 20. Retrieved 1984.
• 4、 Burgess, John,Cartwright, S. James. "". . . Retrieved 1976.
• 5、 McGregor, Donna,Burton-Pye, Benjamin P.,Howell, Robertha C.,Mbomekalle, Israel M.,Lukens, Wayne W.,Bian, Fang,Mausolf, Edward,Poineau, Frederic,Czerwinski, Kenneth R.,Francesconi, Lynn C.. "Synthesis, structure elucidation, and redox properties of 99Tc complexes of lacunary Wells-Dawson polyoxometalates: Insights into molecular 99Tc-metal oxide interactions". . p. 1670 - 1681. Retrieved 2011.
• 6、 Nock,Maina,Tisato,Raptopoulou,Terzis,Chiotellis. "Oxorhenium phosphinophenolato complexes with model peptide fragments: Synthesis, characterization, and stability considerations". . p. 5197 - 5202. Retrieved 2000.
• 7、 Espenson, James H.,Tan, Haisong,Mollah, Sahana,Houk,Eager, Matthew D.. "Base Hydrolysis of Methyltrioxorhenium. The Mechanism Revised and Extended: A Novel Application of Electrospray Mass Spectrometry". . p. 4621 - 4624. Retrieved 1998.
• 8、 Lippert, Cameron A.,Riener, Korbinian,Soper, Jake D.. "Aerobic alcohol oxidations catalyzed by oxorhenium complexes containing redox-active ligands". . p. 554 - 561. Retrieved 2012/03/13.