(4-Methoxyphenyl)(4-methylphenyl)diazene

Base Information

• Chemical Name: (4-Methoxyphenyl)(4-methylphenyl)diazene
• CAS No.: 29418-44-8
• Molecular Formula: C14H14 N2 O
• Molecular Weight: 226.278
• Nikkaji Number: J702.906C,J3.116.842B,J3.116.843K
• Mol file: 29418-44-8.mol

Synonyms:4-Methoxy-4'-methylazobenzene;(4-METHOXYPHENYL)(4-METHYLPHENYL)DIAZENE;29418-44-8;Diazene, 4-methoxyphenyl 4-methylphenyl-;SCHEMBL10813316;SCHEMBL17916164;JBEJCKHKQWNFRA-FOCLMDBBSA-N;(E)-4-Methyl-4'-methoxyazobenzene;(Z)-4-Methyl-4'-methoxyazobenzene;AKOS040824720;(E)-1-(4-Methoxyphenyl)-2-(4-methylphenyl)diazene;(E)-1-(4-Methoxyphenyl)-2-(4-methylphenyl)diazene #

Chemical Property of (4-Methoxyphenyl)(4-methylphenyl)diazene

Chemical Property:

• Vapor Pressure: 5.5E-05mmHg at 25°C
• Boiling Point: 357.8°C at 760 mmHg
• Flash Point: 138.4°C
• Density: 1.05g/cm³
• XLogP3: 4.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 226.110613074
• Heavy Atom Count: 17
• Complexity: 239

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)N=NC2=CC=C(C=C2)OC

Technology Process of (4-Methoxyphenyl)(4-methylphenyl)diazene

There total 16 articles about (4-Methoxyphenyl)(4-methylphenyl)diazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

→ 1-(4-methoxyphenyl)-2-p-tolyldiazene (29418-44-8)

Guidance literature:

With oxygen; In chloroform-d1; at 160 ℃; for 24h; under 4500.45 Torr;

Reference yield: 86.5%

1-methyl-4-nitrosobenzene (623-11-0) + 4-methoxy-aniline (104-94-9) → 1-(4-methoxyphenyl)-2-p-tolyldiazene (29418-44-8)

Guidance literature:

In ethanol; acetic acid; at 50 ℃; for 0.5h;

DOI:10.1246/bcsj.60.3814

Reference yield: 80.0%

para-methoxynitrobenzene (100-17-4) + 1-methyl-4-nitrobenzene (99-99-0) → 1-(4-methoxyphenyl)-2-p-tolyldiazene (29418-44-8)

Guidance literature:

With chloro-trimethyl-silane; samarium diiodide; tetra-(n-butyl)ammonium iodide; tert-butylammonium hexafluorophosphate(V); In tetrahydrofuran; at 20 ℃; for 5h; Electrochemical reaction;

DOI:10.1021/acscatal.7b02940

upstream raw materials:

ethanol

N-(4-methoxy-phenyl)-N'-p-tolyl-hydrazine

1-methyl-4-nitrosobenzene

4-methoxy-aniline

Downstream raw materials:

N-(4-methoxy-phenyl)-N'-p-tolyl-hydrazine

2-(4-methylphenylsulfonamido)-4-methoxy-4'-methylazobenzene

4-methoxy-ONN-4'-methylazoxybenzene

4-methoxy-NNO-4'-methylazoxybenzene

Refernces

• 1、 Akinnawo, Christianah Aarinola,Alimi, Oyekunle Azeez,Fapojuwo, Dele Peter,Meijboom, Reinout,Mogudi, Batsile M.,Onisuru, Oluwatayo Racheal,Oseghale, Charles O.. "Bifunctional Cs?Au/Co3O4 (Basic and Redox)-Catalyzed Oxidative Synthesis of Aromatic Azo Compounds from Anilines". supporting information. p. 5063 - 5073. Retrieved 2021/09/30.
• 2、 Dai, Yitao,Li, Chao,Shen, Yanbin,Zhu, Shujie,Hvid, Mathias S.,Wu, Lai-Chin,Skibsted, J?rgen,Li, Yongwang,Niemantsverdriet, J. W. Hans,Besenbacher, Flemming,Lock, Nina,Su, Ren. "Efficient Solar-Driven Hydrogen Transfer by Bismuth-Based Photocatalyst with Engineered Basic Sites". supporting information. p. 16711 - 16719. Retrieved 2018/12/11.