Bis(2-pyridyl) ketone oxime

Base Information

• Chemical Name: Bis(2-pyridyl) ketone oxime
• CAS No.: 1562-95-4
• Molecular Formula: C11H9 N3 O
• Molecular Weight: 199.212
• Hs Code.: 2933399090
• European Community (EC) Number: 216-349-9
• NSC Number: 155179
• UNII: 6CW6XQN622
• DSSTox Substance ID: DTXSID30935391
• Nikkaji Number: J206.797H
• Mol file: 1562-95-4.mol

Synonyms:di-2-pyridylketoxime

Chemical Property of Bis(2-pyridyl) ketone oxime

Chemical Property:

• Vapor Pressure: 3.69E-05mmHg at 25°C
• Melting Point: 142-143oC(lit.)
• Boiling Point: 353oC at 760 mmHg
• Flash Point: 167.3oC
• PSA: 58.37000
• Density: 1.21g/cm3
• LogP: 1.70320
• Storage Temp.: 2-8°C
• XLogP3: 2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 199.074561919
• Heavy Atom Count: 15
• Complexity: 210

Purity/Quality:

98%,99%, ^*data from raw suppliers

Di-2-pyridyl Ketoxime ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=NC(=C1)C(=NO)C2=CC=CC=N2
• Uses: Metal-complexing agent Di-2-pyridyl ketone oxime was used as a standard in the metal assay for determination of cobalt. It may be employed as metal-complexing agent.

Technology Process of Bis(2-pyridyl) ketone oxime

There total 3 articles about Bis(2-pyridyl) ketone oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

2,2'-dipyridyl ketone (19437-26-4) + hydroxylamine hydrochloride (5470-11-1) → di-2-pyridyl ketone oxime (1562-95-4)

Guidance literature:

hydroxylamine hydrochloride; With sodium acetate; In water; at 60 ℃; for 1h;

2,2'-dipyridyl ketone; In methanol; at 60 ℃;

DOI:10.1039/c4dt03262d

Reference yield: 93.0%

2,2'-dipyridyl ketone (19437-26-4) → di-2-pyridyl ketone oxime (1562-95-4)

Guidance literature:

With pyridine; hydroxylamine hydrochloride; for 2h; Reflux;

DOI:10.1021/acs.inorgchem.6b02378

Reference yield:

→ di-2-pyridyl ketone oxime (1562-95-4)

Guidance literature:

2,2'-Di-pyridyl-keton, 1. gesaettigte wss. Lsg. Hydroxylamin*HCl, tropfenweise 10percent wss. NaOH, 70-80grad, 2. Erwaermen;

upstream raw materials:

2,2'-dipyridyl ketone

hydroxylamine hydrochloride

Downstream raw materials:

C₂₂H₂₀N₄O₄

Refernces

• 1、 Warad, Ismail,Abdoh, Muneer,Al Ali, Anas,Shivalingegowda, Naveen,Kumara, Karthik,Zarrouk, Abdelkader,Lokanath, Neartur Krishnappagowda. "Synthesis, spectra and X-ray crystallography of dipyridin-2-ylmethanone oxime and its CuX2(oxime)2 complexes: Thermal, Hirshfeld surface and DFT analysis". . p. 619 - 625. Retrieved 2018.
• 2、 Unjaroen, Duenpen,Swart, Marcel,Browne, Wesley R.. "Electrochemical polymerization of iron(III) polypyridyl complexes through C-C coupling of redox non-innocent phenolato ligands". . p. 470 - 479. Retrieved 2017.
• 3、 -. "Near-infrared fluorescent compound, preparation method and application thereof in detection of ferrous ions". Paragraph 0043-0047. . Retrieved 2019/12/25.