Vanadium nitride (VN)

Base Information

• Chemical Name: Vanadium nitride (VN)
• CAS No.: 24646-85-3
• Deprecated CAS: 1000296-18-3,1619986-70-7
• Molecular Formula: NV
• Molecular Weight: 64.9482
• European Community (EC) Number: 246-382-4
• Wikipedia: Vanadium nitride
• Wikidata: Q2277900
• Mol file: 24646-85-3.mol

Synonyms:Vanadium nitride;Vanadium nitride (VN);24646-85-3;azanylidynevanadium;EINECS 246-382-4;MFCD00049701;vanadium(III) nitride;VANADIUM NITRIDE (99.5%-V);Boron Carbide (B4C) Sputtering Targets;Q2277900;N-V

Chemical Property of Vanadium nitride (VN)

Chemical Property:

• Melting Point: 2320oC
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 23.79000
• Density: g/cm³
• LogP: 0.01508
• Water Solubility.: insoluble H2O; soluble aqua regia [HAW93]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 64.947032
• Heavy Atom Count: 2
• Complexity: 10

Purity/Quality:

98% ^*data from raw suppliers

Vanadium nitride (99%-V) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22
• Safety Statements: 36

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: N#[V]
• Uses: Vanadium nitride (VN) and TiN exhibit a relatively high critical temperature in superconducting phenomena.

Technology Process of Vanadium nitride (VN)

There total 8 articles about Vanadium nitride (VN) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

vanadium nitrene monocation (115858-94-1) → pyridin-1-ium (16969-45-2) + vanadium mononitride (24646-85-3)

Guidance literature:

With pyridine; In neat (no solvent, gas phase); proton transfer reaction not observed;; mass spectrometry;;

DOI:10.1021/ja00228a002

Reference yield:

vanadium nitrene monocation (115858-94-1) → vanadium mononitride (24646-85-3) + triethylammonium (17440-81-2)

Guidance literature:

With triethylamine; In neat (no solvent, gas phase); proton transfer reaction;; mass spectrometry;;

DOI:10.1021/ja00228a002

Reference yield:

vanadium nitrene monocation (115858-94-1) → vanadium mononitride (24646-85-3) + Ammonium

Guidance literature:

With NH₃; In neat (no solvent, gas phase); proton transfer reaction not observed;; mass spectrometry;;

DOI:10.1021/ja00228a002

upstream raw materials:

vanadium nitrene monocation

diethylamine

propylamine

vanadium

Refernces

• 1、 Balfour, Walter J.,Merer, Anthony J.,Niki, Hideaki,Simard, Benoit,Hackett, Peter A.. "Rotational fine, and hyperfine analyses of the (0,0) band of the D 3Π-X 3Δ system of vanadium mononitride". . p. 3288 - 3303. Retrieved 1993.
• 2、 Buckner, Steven W.,Gord, James R.,Freiser Ben S.. "Gas-Phase Chemistry of Transition Metal-Imido and -Nitrene Ion Complexes. Oxidative Addition of N-H Bonds in NH3 and Transfer of NH from a Metal Center to an Alkene". . p. 6606 - 6612. Retrieved 2007/10/02.