1,2-DIMETHYLCYCLOHEXANOL

Base Information

• Chemical Name: 1,2-DIMETHYLCYCLOHEXANOL
• CAS No.: 5402-29-9
• Molecular Formula: C8H16O
• Molecular Weight: 128.214
• Hs Code.: 2906199090
• Mol file: 5402-29-9.mol

Synonyms:2,5-Cyclohexadiene-1-carboxylic acid,1,2-dimethyl;dl-1,6-dimethyl-6-carboxy-1,4-cyclohexadiene;dimethylcyclohexanol;1,2-dimethyl-2,5-cyclohexadiene-1-carboxylic acid;1,2-dimethyl-cyclohexan-1-ol;1,4-dihydro-1,2-dimethylbenzoic acid;1,2-dimethyl-cyclohexa-2,5-dienecarboxylic acid;cis-and trans-1,2-dimethylcyclohexanol;1,2-Dimethyl-cyclohexanol;1,2-Dimethyl-cyclohexa-2,5-diencarbonsaeure;

Chemical Property of 1,2-DIMETHYLCYCLOHEXANOL

Chemical Property:

• PSA: 20.23000
• LogP: 1.94750
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

1,2-dimethylcyclohexan-1-ol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2-DIMETHYLCYCLOHEXANOL

There total 31 articles about 1,2-DIMETHYLCYCLOHEXANOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

1,2-epoxy-1,2-dimethyl-cyclohexane (17612-36-1) → 1,2-dimethylcyclohexanol (5402-29-9)

Guidance literature:

With lithium aluminium tetrahydride; aluminium trichloride; In diethyl ether; for 4h; Ambient temperature;

DOI:10.1055/s-1983-30550

Reference yield: 91.0%

2-Methylcyclohexanone (583-60-8) + C15H33CeO2 → 1,2-dimethylcyclohexanol (5402-29-9)

Guidance literature:

In tetrahydrofuran; at -78 ℃; for 0.5h;

DOI:10.1002/anie.199724801

Reference yield: 90.0%

3,4-Dimethyl-2-oxatricyclo<5.3.0.01.3>decan (108507-76-2) → 1,2-dimethylcyclohexanol (5402-29-9)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; for 16h;

DOI:10.1021/jo00149a003

upstream raw materials:

methyl magnesium iodide

2-Methylcyclohexanone

1,2-epoxy-1-methylcyclohexane

methyllithium

Downstream raw materials:

1,2-dimethylcyclohexene

1,6-dimethyl-1-cyclohexene

2-methyl-1-methylenecyclohexane

1-methyl-cis-2-methylcyclohexanecarboxylic acid

Refernces

• 1、 Bondarenko, Olena E.,Nesterov, Dmytro S.,Nesterova, Oksana V.,Pombeiro, Armando J. L.. "Phenoxazinone synthase-like catalytic activity of novel mono- And tetranuclear copper(ii) complexes with 2-benzylaminoethanol". . p. 4710 - 4724. Retrieved 2020/04/27.
• 2、 Das, Biswanath,Al-Hunaiti, Afnan,Haukka, Matti,Demeshko, Serhiy,Meyer, Steffen,Shteinman, Albert A.,Meyer, Franc,Repo, Timo,Nordlander, Ebbe. "Catalytic Oxidation of Alkanes and Alkenes by H2O2 with a μ-Oxido Diiron(III) Complex as Catalyst/Catalyst Precursor". . p. 3590 - 3601. Retrieved 2015/08/06.