Einecs 227-013-6

Base Information

• Chemical Name: Einecs 227-013-6
• CAS No.: 5599-32-6
• Molecular Formula: C6H15 N3 Si
• Molecular Weight: 157.291
• Mol file: 5599-32-6.mol

Synonyms:EINECS 227-013-6

Chemical Property of Einecs 227-013-6

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 49.75000
• Density: g/cm³
• LogP: 2.75466
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 157.103524026
• Heavy Atom Count: 10
• Complexity: 128

Purity/Quality:

98%Min ^*data from raw suppliers

TRIETHYLAZIDOSILANE 97.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[Si](CC)(CC)N=[N+]=[N-]

Technology Process of Einecs 227-013-6

There total 2 articles about Einecs 227-013-6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

triethylsilyl chloride (994-30-9) → triethylsilyl azide (5599-32-6)

Guidance literature:

With sodium azide; AMBERLITE XAD-4; In dichloromethane; at 40 ℃; for 6h;

DOI:10.1021/jo00255a041

Reference yield:

→ triethylsilyl azide (5599-32-6)

Guidance literature:

entspr. Silan, Azid;

Reference yield: 40.0%

2-methyl-3-phenyloxirane-2-carbaldehyde (959628-18-3) + triethylsilyl azide (5599-32-6) → C17H27N3O2Si

Guidance literature:

2-methyl-3-phenyloxirane-2-carbaldehyde; triethylsilyl azide; With 2-pentafluorophenyl-6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-2-ium tetrafluoroborate; triethylamine; tert-butyl alcohol; In toluene; at 23 ℃; for 20h; Inert atmosphere;

optical yield given as %de; diastereoselective reaction; Inert atmosphere;

DOI:10.1021/jo8020055

upstream raw materials:

triethylsilyl chloride

Refernces

• 1、 Sukata, Kazuaki. "Efficient Synthesis of Silyl Azides Using Sodium Azide Impregnated on Amberlite XAD Resin". . p. 4867 - 4869. Retrieved 2007/10/02.