8-Quinolinamine, N-8-quinolinyl-

Base Information

• Chemical Name: 8-Quinolinamine, N-8-quinolinyl-
• CAS No.: 88783-63-5
• Molecular Formula: C18H13N3
• Molecular Weight: 271.321
• DSSTox Substance ID: DTXSID80463598
• Nikkaji Number: J1.620.302E
• Wikidata: Q82288559
• Mol file: 88783-63-5.mol

Synonyms:Di(quinolin-8-yl)amine;88783-63-5;8-Quinolinamine, N-8-quinolinyl-;bis(8-quinolinyl)amine;SCHEMBL379216;DTXSID80463598;SB69062

Chemical Property of 8-Quinolinamine, N-8-quinolinyl-

Chemical Property:

• XLogP3: 4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 271.110947427
• Heavy Atom Count: 21
• Complexity: 313

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC2=C(C(=C1)NC3=CC=CC4=C3N=CC=C4)N=CC=C2

Technology Process of 8-Quinolinamine, N-8-quinolinyl-

There total 1 articles about 8-Quinolinamine, N-8-quinolinyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

8-quinolinol (148-24-3,24804-14-6) → 8-amino quinoline (578-66-5) + N-(1,2,3,4-tetrahydroquinolin-8-yl)quinolin-8-amine + bis-(8-quinolinyl)amine (88783-63-5)

Guidance literature:

With palladium on activated carbon; sodium formate; hydrazine hydrate; trifluoroacetic acid; In toluene; at 150 ℃; for 24h; Sealed tube; Inert atmosphere;

DOI:10.1002/adsc.201700712

Reference yield: 86.0%

dichloro(2,2':6',2-terpyridine)(triphenylphosphino)ruthenium(II) (72905-34-1,1100716-05-9,72937-76-9) + sodium tetraphenyl borate (143-66-8) + bis-(8-quinolinyl)amine (88783-63-5) → [(2,2',2''-terpyridine)Ru(bis(8-quinolinyl)amide)][BPh4] (1091616-15-7)

Guidance literature:

With triethylamine; In ethanol; dichloromethane; under N2 atm. soln. ligand and Et3N in CH2Cl2 was added to soln. Ru complex and NaBPh4 in EtOH at room temp. and heated at 65°C for 15 h; react. mixt. was cooled to room temp., residue was washed with Et2O and petroleum ether and dried in vacuo; elem. anal.;

DOI:10.1021/ic801047s

Reference yield: 71.0%

sodium tetraphenyl borate (143-66-8) + iron(III) chloride (7705-08-0) + bis-(8-quinolinyl)amine (88783-63-5) → [Fe(bis(8-quinolinyl)amide)2][BPh4] (1091616-09-9)

Guidance literature:

With Na₂CO₃; In dichloromethane; water; under N2 atm. to slurry ligand and FeCl3 in CH2Cl2 soln. Na2CO3 and NaBPh4 in water was added and stirred for 20 h at room temp.; product was extd. into CH2Cl2 and washed with water and evapd. to dryness; elem. anal.;

DOI:10.1021/ic801047s

upstream raw materials:

8-quinolinol

Downstream raw materials:

[(2,2',2''-terpyridine)Ru(bis(8-quinolinyl)amide)][BPh₄]

[Fe(bis(8-quinolinyl)amide)2][BPh₄]

C₁₈H₁₂ClCuN₃

Refernces