Ethyltriphenylphosphonium acetate

Base Information

• Chemical Name: Ethyltriphenylphosphonium acetate
• CAS No.: 35835-94-0
• Molecular Formula: C20H20P^.C2H3O2
• Molecular Weight: 350.397
• European Community (EC) Number: 252-743-7
• DSSTox Substance ID: DTXSID8067945
• Mol file: 35835-94-0.mol

Synonyms:Ethyltriphenylphosphonium acetate;35835-94-0;ethyl(triphenyl)phosphanium;acetate;ethyl-tri(phenyl)phosphanium acetate;Phosphonium, ethyltriphenyl-, acetate;Ethyltriphenylphosphonium acetate, 70% in methanol;EINECS 252-743-7;Phosphonium, ethyltriphenyl-, acetate (1:1);ethyl(triphenyl)phosphonium acetate;Ethyltriphenylphosphoniumacetate;ethyl(triphenyl)phosphanium,acetate;Ethyltriphenylphosphonium Acid Acetate;SCHEMBL133341;DTXSID8067945;C22H23O2P;ethyltriphenyl phosphonium acetate;C20H20P.C2H3O2;Ethyl-Triphenyl-Phosphanium Acetate;Ethyltriphenylphosponium acid acetate;MFCD00061389;AKOS015896112;C20-H20-P.C2-H3-O2;Ethyl Triphenyl Phosphonium Acid Acetate;CS-0153893;FT-0651919;A822993;W-110868

Chemical Property of Ethyltriphenylphosphonium acetate

Chemical Property:

• Appearance/Colour: White to almost white solid
• Vapor Pressure: 0Pa at 25℃
• Melting Point: 163?°C (dec.)(lit.)
• Boiling Point: 63oC
• Flash Point: -17°(0°F)
• PSA: 53.72000
• Density: 1.05
• LogP: 2.75660
• Water Solubility.: Soluble in water, alcohol.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 350.14356697
• Heavy Atom Count: 25
• Complexity: 273

Purity/Quality:

99% ^*data from raw suppliers

ETHYL TRIPHENYLPHOSPHONIUM ACID ACETATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,F
• Hazard Codes: T,F

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.CC(=O)[O-]

Technology Process of Ethyltriphenylphosphonium acetate

There total 1 articles about Ethyltriphenylphosphonium acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

potassium acetate (127-08-2) + ethyltriphenylphosphonium chloride (896-33-3) → ethyltriphenylphosphonium acetate (35835-94-0)

Guidance literature:

In ethanol; at 20 ℃; for 16.33h; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.orglett.1c00133

Reference yield:

ethyltriphenylphosphonium acetate (35835-94-0) + benzaldehyde (100-52-7) → 1-phenylpropene (637-50-3)

Guidance literature:

In dimethyl sulfoxide; at 30 ℃; Kinetics; Inert atmosphere;

DOI:10.1055/s-0037-1610788

upstream raw materials:

potassium acetate

ethyltriphenylphosphonium chloride

Downstream raw materials:

1-phenylpropene

Refernces