Lithium hydroxide monohydrate

Base Information

• Chemical Name: Lithium hydroxide monohydrate
• CAS No.: 1310-66-3
• Molecular Formula: LiOH^.H2O
• Molecular Weight: 41.9636
• Hs Code.: 2825201000
• European Community (EC) Number: 603-454-3,624-580-5
• ICSC Number: 0914
• UN Number: 2680
• UNII: G51XLP968G
• DSSTox Substance ID: DTXSID8051382
• Wikidata: Q12451415
• Mol file: 1310-66-3.mol

Synonyms:lithium hydroxide;lithium hydroxide monohydrate;lithium hydroxide, 6Li-labeled;lithium hydroxide, 7Li-labeled

Chemical Property of Lithium hydroxide monohydrate

Chemical Property:

• Appearance/Colour: colourless, hygroscopic crystals
• Melting Point: 462 °C
• Boiling Point: 100 °C at 760 mmHg
• PSA: 32.29000
• Density: 1.51 g/cm³
• LogP: -0.24110
• Water Solubility.: 109 g/L (20℃)
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 42.02930777
• Heavy Atom Count: 3
• Complexity: 2
• Transport DOT Label: Corrosive

Purity/Quality:

56.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C:Corrosive
• Statements: R20/22:; R35:
• Safety Statements: S22:; S26:; S36/37/39:; S45:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: [Li+].O.[OH-]
• Inhalation Risk: Evaporation at 20 °C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.
• Effects of Short Term Exposure: The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation may cause lung oedema, but only after initial corrosive effects on eyes and/or airways have become manifest.

Technology Process of Lithium hydroxide monohydrate

There total 18 articles about Lithium hydroxide monohydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Li34.2MnN3.9O13.7 → lithium hydroxide monohydrate (1310-66-3) + manganese(II) oxide + lithium carbonate (554-13-2)

Guidance literature:

In neat (no solvent); stored in open air for 8 wk; detd. by X-ray diffraction;

DOI:10.1021/ic900082u

Reference yield:

Li7.9MnN3.2O1.6 → lithium manganese oxide + lithium hydroxide monohydrate (1310-66-3) + manganese(II) oxide + lithium carbonate (554-13-2)

Guidance literature:

In neat (no solvent); stored in open air for 8 wk; detd. by X-ray diffraction;

DOI:10.1021/ic900082u

Reference yield:

Li1.98Mn1.01Se1001O1.01 + water (7732-18-5) → manganese(II) selenide + manganese(II) hydroxide + lithium hydroxide monohydrate (1310-66-3) + lithium selenide (12136-60-6)

Guidance literature:

With air; at 20 ℃; for 0.5h;

DOI:10.1021/acs.inorgchem.8b01850

upstream raw materials:

water

lithium hydroxide

lithium carbonate

n-butyllithium

Downstream raw materials:

nickel(II) oxide

lithium carbonate

lithium aluminate

lithium molybdate

Refernces

• 1、 Hwang, Seong-Ju,Kwon, Chai-Won,Portier, Josik,Campet, Guy,Park, Hyo-Suk,Choy, Jin-Ho,Huong, Pham V.,Yoshimura, Masahiro,Kakihana, Masato. "Local crystal structure around manganese in new potassium-based nanocrystalline manganese oxyiodide". . p. 4053 - 4060. Retrieved 2002.
• 2、 Cabana, Jordi,Dupre, Nicolas,Gillot, Frederic,Chadwick, Alan V.,Grey, Clare P.,Palacin, M. Rosa. "Synthesis, short-range structure, and electrochemical properties of new phases in the Li-Mn-N-0 system". . p. 5141 - 5153. Retrieved 2009.
• 3、 Lai, Kwing To,Antonyshyn, Iryna,Prots, Yurii,Valldor, Martin. "Extended Chemical Flexibility of Cubic Anti-Perovskite Lithium Battery Cathode Materials". supporting information. p. 13296 - 13299. Retrieved 2018/10/31.