Pentanedioyl dichloride

Base Information

• Chemical Name: Pentanedioyl dichloride
• CAS No.: 2873-74-7
• Deprecated CAS: 128347-54-6
• Molecular Formula: C5H6Cl2O2
• Molecular Weight: 169.007
• Hs Code.: 29171900
• European Community (EC) Number: 220-711-1
• NSC Number: 519867
• UNII: 6PPM7UQR7V
• DSSTox Substance ID: DTXSID1062679
• Nikkaji Number: J149.591G
• Wikipedia: Glutaryl_chloride
• Wikidata: Q63179337
• Mol file: 2873-74-7.mol

Synonyms:Glutaryl dichloride;Pentanedioyl dichloride;GLUTARYL CHLORIDE;2873-74-7;Glutaric acid dichloride;Glutaroyl chloride;Glutaroyl dichloride;Glutaryldichloride;1,3-Bis(chlorocarbonyl)propane;EINECS 220-711-1;6PPM7UQR7V;NSC 519867;NSC-519867;glutaric acid chloride;Glutaryl chloride, 97%;UNII-6PPM7UQR7V;1,5-Pentanedioyl chloride;SCHEMBL180666;Glutaryl chloride (7CI,8CI);DTXSID1062679;YVOFTMXWTWHRBH-UHFFFAOYSA-;5-Chloro-5-oxopentanoyl chloride;CAA87374;MFCD00000755;NSC519867;AKOS009031471;AS-10508;LS-101720;FT-0600472;G0202;Glutaryl chloride, technical, >=97.0% (T);F53553;J-017228

Chemical Property of Pentanedioyl dichloride

Chemical Property:

• Appearance/Colour: clear colorless to yellow or red-brownish liquid
• Vapor Pressure: 0.13mmHg at 25°C
• Refractive Index: n20/D 1.472(lit.)
• Boiling Point: 217.8 °C at 760 mmHg
• Flash Point: 106.7 °C
• PSA: 34.14000
• Density: 1.319 g/cm³
• LogP: 1.68750
• Sensitive.: Moisture Sensitive
• XLogP3: 1.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 167.9744848
• Heavy Atom Count: 9
• Complexity: 108

Purity/Quality:

99% ^*data from raw suppliers

Glutaryl chloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 22-34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Toxic Gases & Vapors -> Acid Halides
• Canonical SMILES: C(CC(=O)Cl)CC(=O)Cl

Technology Process of Pentanedioyl dichloride

There total 7 articles about Pentanedioyl dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

1,5-pentanedioic acid (110-94-1) → gloutaric dichloride (2873-74-7)

Guidance literature:

With thionyl chloride; at 20 ℃;

DOI:10.1039/c3cc41225c

Reference yield: 82.0%

glutaric anhydride, (108-55-4) → gloutaric dichloride (2873-74-7)

Guidance literature:

With phosphorus pentachloride; for 24h; Reflux;

DOI:10.1016/j.tetasy.2013.03.021

Reference yield:

1,5-pentanedioic acid (110-94-1) + Adipic acid (124-04-9) + succinic acid (110-15-6) → gloutaric dichloride (2873-74-7) + succinoyl dichloride (543-20-4) + Adipic acid dichloride (111-50-2)

Guidance literature:

With thionyl chloride; at 20 ℃;

upstream raw materials:

1,5-pentanedioic acid

thionyl chloride

1 ,5-pentanediol

Glutaronitrile

Downstream raw materials:

N,N,N′,N′-tetramethylglutaramide

1,5-dimesityl-pentane-1,5-dione

1,5-diphenyl-1,5-pentanedione

5-oxo-5-phenylvaleric acid

Refernces

• 1、 Galoppini,Chebolu,Gilardi,Zhang. "Copper(I)-catalyzed [2 + 2] photocycloadditions with tethered linkers: Synthesis of syn-photodimers of dicyclopentadienes". . p. 162 - 168. Retrieved 2001.
• 2、 Yan, Liying,Xiong, Chaochao,Jin, Piaopiao,Luo, Qianfu. "Fluorescent molecular photoswitch based on basket-shaped porphyrins". supporting information. . Retrieved 2020/07/03.
• 3、 Yu, Fei,Liu, Wenbo,Li, Bang,Tian, Dan,Zuo, Jing-Lin,Zhang, Qichun. "Photostimulus-Responsive Large-Area Two-Dimensional Covalent Organic Framework Films". supporting information. p. 16101 - 16104. Retrieved 2019/11/05.