PENTABROMOBENZYL ACRYLATE

Base Information

• Chemical Name: PENTABROMOBENZYL ACRYLATE
• CAS No.: 59447-55-1
• Molecular Formula: C10H5Br5O2
• Molecular Weight: 556.668
• European Community (EC) Number: 261-767-7
• UNII: K55L5VE7PP
• DSSTox Substance ID: DTXSID9052719
• Nikkaji Number: J298.162I
• Wikidata: Q81985171
• Mol file: 59447-55-1.mol

Synonyms:Pentabromobenzyl acrylate;(Pentabromophenyl)methyl acrylate;

Chemical Property of PENTABROMOBENZYL ACRYLATE

Chemical Property:

• Vapor Pressure: 2.73E-09mmHg at 25°C
• Melting Point: 115-116 °C
• Refractive Index: 1.644
• Boiling Point: 477.7 °C at 760 mmHg
• Flash Point: 242.7 °C
• PSA: 26.30000
• Density: 2.371 g/cm³
• LogP: 5.60340
• Storage Temp.: 2-8°C
• Solubility.: soluble in Toluene
• Water Solubility.: 8.7μg/L at 20℃
• XLogP3: 5.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 555.61654
• Heavy Atom Count: 17
• Complexity: 282

Purity/Quality:

99.9% ^*data from raw suppliers

Pentabromobenzyl acrylate ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C=CC(=O)OCC1=C(C(=C(C(=C1Br)Br)Br)Br)Br
• Uses: Pentabromobenzyl Acrylate is a flame retardant and a standard for environmental testing and research. Pentabromobenzyl acrylate can form copolymers with styrene. Polymerization of the monomer in methyl ethyl ketone can yield novel, flame retardant nano/micro sized (0.06 ± 0.01 and 1.70 ± 0.23 μm) particles. Polyamide (PA6) treated with PMA and montorillonite (OMMT) has been described in a study.

Technology Process of PENTABROMOBENZYL ACRYLATE

There total 3 articles about PENTABROMOBENZYL ACRYLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

→ pentabromobenzyl acrylate (59447-55-1)

Guidance literature:

Reference yield: 93.5%

2,3,4,5,6-pentabromobenzyl bromide (38521-51-6) + acrylic acid (79-10-7) → pentabromobenzyl acrylate (59447-55-1)

Guidance literature:

With sodium 2-propenoate; In 2-methoxy-ethanol; at 100 ℃; for 3h; pH=6.5;

DOI:10.1039/c7ra11461c

Reference yield:

2,3,4,5,6-pentabromobenzyl bromide (38521-51-6) + sodium 2-propenoate (7446-81-3) → pentabromobenzyl acrylate (59447-55-1)

Guidance literature:

With tetrabutylammomium bromide; In water; chlorobenzene; at 20 - 95 ℃; for 3.25h; Time;

upstream raw materials:

2,3,4,5,6-pentabromobenzyl bromide

sodium 2-propenoate

acrylic acid

Refernces

• 1、 -. "PROCESS FOR THE PREPARATION OF THE MONOMER PENTABROMOBENZYL ACRYLATE AND POLYMERIZATION THEREOF". Paragraph 0053; 0054; 0055; 0056; 0057; 0058. . Retrieved 2014/05/08.