Tributylcyclopenta-2,4-dienylstannane

Base Information

• Chemical Name: Tributylcyclopenta-2,4-dienylstannane
• CAS No.: 3912-86-5
• Molecular Formula: C17H32 Sn
• Molecular Weight: 355.151
• European Community (EC) Number: 223-469-5
• UNII: 2SB89EFH84
• DSSTox Substance ID: DTXSID00192373
• Mol file: 3912-86-5.mol

Synonyms:3912-86-5;Tributylcyclopenta-2,4-dienylstannane;tributyl(cyclopenta-2,4-dien-1-yl)stannane;2SB89EFH84;EINECS 223-469-5;UNII-2SB89EFH84;DTXSID00192373;Stannane, tributyl-2,4-cyclopentadien-1-yl-;TRIBUTYL-2,4-CYCLOPENTADIEN-1-YLSTANNANE

Chemical Property of Tributylcyclopenta-2,4-dienylstannane

Chemical Property:

• Vapor Pressure: 6.76E-05mmHg at 25°C
• Refractive Index: 1.515
• Boiling Point: 132-133°C 1mm
• Flash Point: >110°C
• PSA: 0.00000
• LogP: 5.63530
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 10
• Exact Mass: 356.152604
• Heavy Atom Count: 18
• Complexity: 231

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

Useful:

• Canonical SMILES: CCCC[Sn](CCCC)(CCCC)C1C=CC=C1

Technology Process of Tributylcyclopenta-2,4-dienylstannane

There total 2 articles about Tributylcyclopenta-2,4-dienylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.5%

dimethylamino tributyltin (1067-24-9) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) → (tri-n-butylstannyl)cyclopentadiene (3912-86-5)

Guidance literature:

20°C;;

DOI:10.1016/S0022-328X(00)84649-5

Reference yield:

tributyltin chloride (1461-22-9) → (tri-n-butylstannyl)cyclopentadiene (3912-86-5)

Guidance literature:

With sodium cyclopentadienide; In benzene; 25°C, 2 days;;

DOI:10.1016/S0022-328X(00)80058-3

Reference yield: 79.0%

[(η(5)-C5H5)NbCl4] + (tri-n-butylstannyl)cyclopentadiene (3912-86-5) → niobocene dichloride (12793-14-5)

Guidance literature:

In dichloromethane; stirred for 4 d at room temp.; concd. (vac.), toluene added, filtered after 1 h, crystals washed with toluene, dried (vac.);

DOI:10.1016/S0022-328X(00)90294-8

upstream raw materials:

dimethylamino tributyltin

cyclopenta-1,3-diene

tributyltin chloride

Downstream raw materials:

niobocene dichloride

bis(η⁵-cyclopentadienyl)ruthenium

(C₄H₉)3SnONOC₆H₄Cl-4

(C₅H₅)(C₅H₄CH(CH₃)C₆H₅)NbCl₂