CHRYSENE-TRANS-5,6-DIHYDRODIOL

Base Information

• Chemical Name: CHRYSENE-TRANS-5,6-DIHYDRODIOL
• CAS No.: 56183-24-5
• Molecular Formula: C₁₈H₁₄O₂
• Molecular Weight: 262.308
• Mol file: 56183-24-5.mol

Synonyms:5,6-Chrysenediol,5,6-dihydro-, trans-

Chemical Property of CHRYSENE-TRANS-5,6-DIHYDRODIOL

Chemical Property:

• Vapor Pressure: 1E-10mmHg at 25°C
• Boiling Point: 497.7°Cat760mmHg
• Flash Point: 242.7°C
• PSA: 40.46000
• Density: 1.35g/cm³
• LogP: 3.58720

Purity/Quality:

99% ^*data from raw suppliers

CHRYSENE-TRANS-5,6-DIHYDRODIOL 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of CHRYSENE-TRANS-5,6-DIHYDRODIOL

There total 13 articles about CHRYSENE-TRANS-5,6-DIHYDRODIOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5,6-chrysenedione (2051-10-7) → (+)-chrysene (5S,6S)-dihydrodiol (77123-20-7,56183-24-5,82041-83-6)

Guidance literature:

Multi-step reaction with 2 steps

1: KBH₄ / propan-2-ol / Ambient temperature

With potassium borohydride; In isopropyl alcohol;

DOI:10.1021/jo00360a024

Reference yield:

5,6-chrysenedione (2051-10-7) → (-)-chrysene (5R,6R)-dihydrodiol (101313-23-9,56183-24-5,82041-83-6)

Guidance literature:

Multi-step reaction with 2 steps

1: KBH₄ / propan-2-ol / Ambient temperature

With potassium borohydride; In isopropyl alcohol;

DOI:10.1021/jo00360a024

Reference yield:

5,6-chrysenedione (2051-10-7) → (+/-)-chrysene cis-5,6-dihydrodiol (101313-29-5,56183-24-5,82041-83-6) + (+/-)-chrysene trans-5,6-dihydrodiol (67175-78-4,56183-24-5,82041-83-6)

Guidance literature:

With potassium borohydride; In isopropyl alcohol; Ambient temperature;

DOI:10.1021/jo00360a024

upstream raw materials:

(+/-)-chrysene trans-5,6-dihydrodiol

5,6-chrysenedione

(+/-)-chrysene cis-5,6-dihydrodiol

chrysene

Downstream raw materials:

(-)-cis-chrysene-5(R),6(S)-dihydrodiol

(+)-cis-chrysene-5(S),6(R)-dihydrodiol

(+)-chrysene (5S,6S)-dihydrodiol

(-)-chrysene (5R,6R)-dihydrodiol

Refernces

• 1、 Balani, S. K.,Bladeren, P. J. van,Shirai, N.,Jerina, D. M.. "Resolution and Absolute Configuration of K-Region Trans Dihydrodiols from Polycyclic Aromatic Hydrocarbons". . p. 1773 - 1778. Retrieved 2007/10/02.