Chlorodifluoroborane

Base Information

• Chemical Name: Chlorodifluoroborane
• CAS No.: 14720-30-0
• Molecular Formula: BClF2
• Molecular Weight: 100.715
• DSSTox Substance ID: DTXSID50163619
• Wikidata: Q83032569
• Mol file: 14720-30-0.mol

Synonyms:Chlorodifluoroborane;14720-30-0;BClF2;Chlorodifluoro-;ARGRMFKYCQHOAU-UHFFFAOYA;Chlorodifluoro-borane;DTXSID50163619;InChI=1/BClF2/c2-1(3)4

Chemical Property of Chlorodifluoroborane

Chemical Property:

• Refractive Index: 1.23
• Density: 1.157 g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 83.9749642
• Heavy Atom Count: 4
• Complexity: 13.5

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(F)(F)Cl

Technology Process of Chlorodifluoroborane

There total 5 articles about Chlorodifluoroborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 13.0%

trichlorofluoromethane (75-69-4) + boron trichloride (10294-34-5) → boron trifluoride (7637-07-2) + boron difluoridechloride (14720-31-1) + boron fluoridedichloride (14720-30-0)

Guidance literature:

In neat (no solvent); heating of BCl3 and CFCl3 in an evacuated sealed tube at 65°C. for 283 h, then 4 h at 130°C; products detected by (11)B- and (19)F-NMR;

Reference yield:

B10F12 + boron trichloride (10294-34-5) → nonachlorononaborane(9) (12008-47-8) + boron trifluoride (7637-07-2) + boron difluoridechloride (14720-31-1) + boron fluoridedichloride (14720-30-0)

Guidance literature:

In dichloromethane-d2; B salts mixed at o°C, warmed to 60°C, extd.(CD2Cl2); NMR;

DOI:10.1016/S0277-5387(01)01032-4

Reference yield:

B8F12 + boron trichloride (10294-34-5) → nonachlorononaborane(9) (12008-47-8) + boron trifluoride (7637-07-2) + boron difluoridechloride (14720-31-1) + boron fluoridedichloride (14720-30-0)

Guidance literature:

In dichloromethane-d2; B salts mixed at o°C, warmed to 60°C, extd.(CD2Cl2); NMR;

DOI:10.1016/S0277-5387(01)01032-4

upstream raw materials:

trichlorofluoromethane

boron trichloride

Downstream raw materials:

lithium bis[1,2-oxalato^(2-)-O,O'] borate

Refernces

• 1、 Saulys,Castillo,Morrison. "Fluorination of boron chlorides and boron bromides by reaction with bis(trifluoromethyl)mercury, trichlorofluoromethane, or tribromofluoromethane: Synthesis of BF2B5H8". . p. 1619 - 1624. Retrieved 2008/10/08.