Lutetium trifluoride

Base Information

• Chemical Name: Lutetium trifluoride
• CAS No.: 13760-81-1
• Molecular Formula: LuF3
• Molecular Weight: 231.962
• Hs Code.: 28469000
• European Community (EC) Number: 237-355-8
• DSSTox Substance ID: DTXSID8065614
• Wikipedia: Lutetium(III)_fluoride,Lutetium trifluoride
• Wikidata: Q15632886
• Mol file: 13760-81-1.mol

Synonyms:Lutetium fluoride;Lutetium trifluoride;13760-81-1;trifluorolutetium;Lutetium fluoride (LuF3);Lutetium(III) fluoride;EINECS 237-355-8;Lutetium(III) fluoride, REacton?;MFCD00016191;F3Lu;F3-Lu;UNII-I36LOL46B6;DTXSID8065614;LS-88364;FT-0628050;Q15632886;Lutetium(III) fluoride, anhydrous, powder, 99.99% trace metals basis

Chemical Property of Lutetium trifluoride

Chemical Property:

• Appearance/Colour: white fine crystalline powder
• Melting Point: 1182 °C
• Boiling Point: 2200oC
• PSA: 0.00000
• Density: 8.332
• LogP: 1.26060
• Sensitive.: Hygroscopic
• Water Solubility.: insoluble H2O [HAW93]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 231.93599
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Lutetium(III) fluoride anhydrous, powder, 99.99% trace metals basis ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 23/24/25-32
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Rare Earth Metals
• Canonical SMILES: F[Lu](F)F
• Uses: Lutetium Fluoride is applied in making laser crystal, and also have specialized uses in ceramics, glass, phosphors, lasers, also be used as catalysts in cracking, alkylation, hydrogenation, and polymerization. Stable Lutetium can be used as catalysts in petroleum cracking in refineries and can also be used in alkylation, hydrogenation, and polymerization applications.

Technology Process of Lutetium trifluoride

There total 22 articles about Lutetium trifluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

lutetium(III) oxide + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) → lutetium(III) fluoride (13760-81-1)

Guidance literature:

In neat (no solvent); byproducts: H2O; at elevated temp.;;

DOI:10.1021/ja02222a009 DOI:10.1007/BF01481992

Reference yield:

ammonium fluoride + lutetium(III) oxide → lutetium(III) fluoride (13760-81-1)

Guidance literature:

In neat (no solvent); excess fluoride, 200°C, Pt-vessel; removal of excess fluoride on heating in a stream of dry inert gas to 450°C;;

Reference yield:

chlorine trifluoride (7790-91-2) + lutetium(III) oxide → lutetium(III) fluoride (13760-81-1)

Guidance literature:

In neat (no solvent); at room temp. in presence of moisture;;

DOI:10.1021/ja01644a016

upstream raw materials:

xenon difluoride

chlorine trifluoride

hydrogen fluoride

cadmium(II) fluoride

Downstream raw materials:

terbium tetrafluoride

lutetium

Refernces

• 1、 Gong, Yu,Wang, Xuefeng,Andrews, Lester,Chen, Mingyang,Dixon, David A.. "Infrared spectra and quantum chemical calculations of the bridge-bonded HC(F)LnF2 (Ln = La-Lu) complexes". . p. 4443 - 4452. Retrieved 2011/10/10.
• 2、 Yoshimura,Ohara. "Thermochemical studies on the lanthanoid complexes of trifluoroacetic acid". . p. 573 - 576. Retrieved 2008/10/09.