Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-[1,1,2,2,3,3-hexafluoro-3-(trifluoromethoxy)propoxy]-

Base Information

• Chemical Name: Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-[1,1,2,2,3,3-hexafluoro-3-(trifluoromethoxy)propoxy]-
• CAS No.: 58194-00-6
• Molecular Formula: C7F14O3
• Molecular Weight: 398.0507
• DSSTox Substance ID: DTXSID90886254
• Mol file: 58194-00-6.mol

Synonyms:58194-00-6;2-(1,1,2,2,3,3-Hexafluoro-3-(trifluoromethoxy)propoxy)-2,3,3,3-tetrafluoropropanoyl fluoride;Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-[1,1,2,2,3,3-hexafluoro-3-(trifluoromethoxy)propoxy]-;Propanoyl fluoride, 2-(1,1,2,3,3,3-hexafluoro-3-(trifluoromethoxy)propoxy)-2,3,3,3-tetrafluoro-;Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-(1,1,2,2,3,3-hexafluoro-3-(trifluoromethoxy)propoxy)-;SCHEMBL21056622;C7F14O3;DTXSID90886254;C7-F14-O3;LS-123215;perfluoro-2-(4-oxaamyloxy)propionyl fluoride;2,3,3,3-Tetrafluoro-2-[1,1,2,2,3,3-hexafluoro-3-(trifluoromethoxy)propoxy]-propanoyl fluoride

Chemical Property of Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-[1,1,2,2,3,3-hexafluoro-3-(trifluoromethoxy)propoxy]-

Chemical Property:

• Vapor Pressure: 3.05mmHg at 25°C
• Boiling Point: 155.3°Cat760mmHg
• Flash Point: 47.1°C
• PSA: 35.53000
• Density: 1.727g/cm³
• LogP: 4.08450
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 17
• Rotatable Bond Count: 6
• Exact Mass: 397.9623881
• Heavy Atom Count: 24
• Complexity: 478

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)(C(C(F)(F)F)(OC(C(C(OC(F)(F)F)(F)F)(F)F)(F)F)F)F

Technology Process of Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-[1,1,2,2,3,3-hexafluoro-3-(trifluoromethoxy)propoxy]-

There total 2 articles about Propanoyl fluoride, 2,3,3,3-tetrafluoro-2-[1,1,2,2,3,3-hexafluoro-3-(trifluoromethoxy)propoxy]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

Hexafluoropropene oxide (428-59-1,25038-02-2) + perfluoro-3-methoxypropionyl fluoride (425-38-7) → C10F20O4 + 2,3,3,3-tetrafluoro-2-(1,1,2,2,3,3-hexafluoro-3-(trifluoromethoxy)propoxy)propanoyl fluoride (58194-00-6)

Guidance literature:

With potassium fluoride; In diethylene glycol dimethyl ether; at 0 - 10 ℃; for 1h; Product distribution / selectivity;

Reference yield: 77.0%

Hexafluoropropene oxide (428-59-1,25038-02-2) + perfluoro-3-methoxypropionyl fluoride (425-38-7) → 2,3,3,3-tetrafluoro-2-(1,1,2,2,3,3-hexafluoro-3-(trifluoromethoxy)propoxy)propanoyl fluoride (58194-00-6)

Guidance literature:

perfluoro-3-methoxypropionyl fluoride; With potassium fluoride; In diethylene glycol dimethyl ether; at -5 ℃; for 0.5h;

Hexafluoropropene oxide; for 0.5h; Product distribution / selectivity;

Reference yield: 87.6%

2,3,3,3-tetrafluoro-2-(1,1,2,2,3,3-hexafluoro-3-(trifluoromethoxy)propoxy)propanoyl fluoride (58194-00-6) → perfluoro-4-oxaamyl 1,3,3,3-tetrafluoroethyl ether (67784-32-1) + 1,1,2,2,3,3-hexafluoro-1-[(1,2,2-trifluoroethenyl)oxy]-3-(trifluoromethoxy)-propane (40573-09-9)

Guidance literature:

With potassium carbonate; for 1h; Product distribution / selectivity;

upstream raw materials:

Hexafluoropropene oxide

perfluoro-3-methoxypropionyl fluoride

Downstream raw materials:

perfluoro-4-oxaamyl 1,3,3,3-tetrafluoroethyl ether

1,1,2,2,3,3-hexafluoro-1-[(1,2,2-trifluoroethenyl)oxy]-3-(trifluoromethoxy)-propane

Refernces

• 1、 Lebedev,Berenblit,Starobin,Gubanov. "Pyrolytic decarboxylation of some derivatives of perfluorinated mono- and dicarboxylic acids". . p. 1640 - 1645. Retrieved 2007/10/03.