di-n-Hexyl disulfide

Base Information

• Chemical Name: di-n-Hexyl disulfide
• CAS No.: 10496-15-8
• Molecular Formula: C12H26S2
• Molecular Weight: 234.47
• Hs Code.: 2930909090
• European Community (EC) Number: 234-022-9
• NSC Number: 677454
• UNII: X5X7DY36KA
• DSSTox Substance ID: DTXSID60146872
• Nikkaji Number: J97.172C
• ChEMBL ID: CHEMBL120086
• Mol file: 10496-15-8.mol

Synonyms:di-n-Hexyl disulfide;10496-15-8;Dihexyl disulfide;Hexyl disulfide;Disulfide, dihexyl;1-(Hexyldisulfanyl)hexane;Dihexyl disulphide;n-Hexyl disulfide;1,2-dihexyldisulfane;NSC-677454;X5X7DY36KA;EINECS 234-022-9;NSC677454;Disulfide,dihexyl;Dihexyl persulfide;1-Hexyldisulfanyl-hexane;N-HEXYL DISULPHIDE;DISULPHIDE, DIHEXYL;UNII-X5X7DY36KA;1-(Hexyldisulfanyl)hexane #;SCHEMBL114068;CHEMBL120086;DTXSID60146872;C12H26S2;MFCD00027300;AKOS024319274;CS-0440217;F71204

Chemical Property of di-n-Hexyl disulfide

Chemical Property:

• Vapor Pressure: 0.00152mmHg at 25°C
• Melting Point: -47.99°C
• Refractive Index: 1.49
• Boiling Point: 305.1 °C at 760 mmHg
• Flash Point: 126.4 °C
• PSA: 50.60000
• Density: 0.921 g/cm³
• LogP: 5.52840
• XLogP3: 5.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 11
• Exact Mass: 234.14759318
• Heavy Atom Count: 14
• Complexity: 82.3

Purity/Quality:

98%,99%, ^*data from raw suppliers

HEXYL DISULFIDE Aldrich ^*data from reagent suppliers

Safty Information:

• Safety Statements: 23-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCCCSSCCCCCC

Technology Process of di-n-Hexyl disulfide

There total 61 articles about di-n-Hexyl disulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

Hexanethiol (111-31-9) → dihexyl disulfide (10496-15-8)

Guidance literature:

With (tetrabenzoporphinato)iron(II); In tetrahydrofuran; at 20 ℃; for 2h; under 760.051 Torr;

DOI:10.1039/c8ob00908b

Reference yield: 88.0%

1-bromo-hexane (111-25-1) → dihexyl disulfide (10496-15-8)

Guidance literature:

With (C₆H₅CH₂N(Et)3)6Mo₇S₂₄; In chloroform; at 20 ℃; for 10h;

DOI:10.1016/S0040-4039(02)02776-4

Reference yield: 87.0%

C6H13O3S2(1-)*Na(1+) (41051-08-5) → dihexyl disulfide (10496-15-8)

Guidance literature:

With samarium; In water; at 90 ℃; for 4h;

DOI:10.1016/S0040-4039(02)01915-9

upstream raw materials:

1-bromo-hexane

Hexanethiol

9-nitroanthracene

S-hexyl ethanethioate

Downstream raw materials:

allyl n-hexyl sulfide

n-hexyl-vinyl sulfide

2-hexylsulfanyl-3-phenyl-propionaldehyde

2-hexylsulfanylthiophene

Refernces

• 1、 Lee,Choi,Yoon. "Convenient one-pot synthesis of β-alkylthio acid derivatives from thioacetates and the corresponding α,β-unsaturated compounds". . p. 2189 - 2196. Retrieved 1996.
• 2、 Wang, Lei,Li, Pinhua,Zhou, Li. "A novel reduction of sodium alkyl thiosulfates using samarium metal without an activating agent in water". . p. 8141 - 8143. Retrieved 2002.
• 3、 Sato, Tsuneo,Otera, Junzo,Nozaki, Hitosi. "ACTIVATION AND SYNTHETIC APPLICATIONS OF THIOSTANNANES. EFFICIENT CONVERSION OF THIOLS INTO DISULFIDES". . p. 3591 - 3594. Retrieved 1990.
• 4、 Chauhan, Deepak K.,Patnam, Padma L.,Ganguly, Sudip K.,Jain, Suman L.. "A two in one approach: Renewable support and enhanced catalysis for sweetening using chicken feather bound cobalt(II) phthalocyanine under alkali free environment". . p. 51983 - 51988. Retrieved 2016.
• 5、 Guo, Hongyun,Zhan, Zhuangping,Zhang, Yongmin. "Preparation of dialkyl disulfides via reduction of alkylthiocyanates with TiCl4/Sm system". . p. 2721 - 2724. Retrieved 1997.
• 6、 Sato, Tsuneo,Otera, Junzo,Nozaki, Hitosi. "ACTIVATION AND SYNTHETIC APPLICATION OF THIOSTANNANES. EFFICIENT CONVERSION OF THIOL ACETATES INTO DISULFIDES". . p. 3595 - 3596. Retrieved 1990.
• 7、 Kumar, Pawan,Gill, Kareena,Kumar, Sunil,Ganguly, Sudip K.,Jain, Suman L.. "Magnetic Fe3O4@MgAl-LDH composite grafted with cobalt phthalocyanine as an efficient heterogeneous catalyst for the oxidation of mercaptans". . p. 48 - 54. Retrieved 2015.
• 8、 Sidiq, Naheed,Bhat, Mohsin Ahmad,Khan, Khaliquz Zaman,Khuroo, Mohammad Akbar. "Microwave-assisted synthesis of disulfides using tetrathiomolybdate: A step toward greener synthesis". . p. 373 - 376. Retrieved 2012.
• 9、 Yakupov,Shereshovets,Imashev,Ismagilov. "Liquid-phase oxidation of thiols with chlorine dioxide". . p. 2352 - 2355. Retrieved 2001.
• 10、 Yano, Yumihiko,Yatsu, Isao,Oya, Eiichi,Ohshima, Masashi. "HIGH OXIDIZING ACTIVITY OF 8-AZA-3,10-DIMETHYLISOALLOXAZINE (8-AZAFLAVIN)". . p. 775 - 778. Retrieved 1983.