ISO-PROPENYLCYCLOPROPANE

Base Information

• Chemical Name: ISO-PROPENYLCYCLOPROPANE
• CAS No.: 4663-22-3
• Molecular Formula: C6H10
• Molecular Weight: 82.1454
• Hs Code.: 2902199090
• Mol file: 4663-22-3.mol

Synonyms:Propene,2-cyclopropyl- (6CI,7CI,8CI); (1-Methylethenyl)cyclopropane; (a-Methylvinyl)cyclopropane;1-Cyclopropyl-1-methylethene; 1-Cyclopropyl-1-methylethylene;1-Methyl-1-cyclopropylethylene; 2-Cyclopropyl-1-propene; 2-Cyclopropylpropene;Isopropenylcyclopropane; NSC 5216

Chemical Property of ISO-PROPENYLCYCLOPROPANE

Chemical Property:

• Vapor Pressure: 159mmHg at 25°C
• Melting Point: -102.3°C
• Refractive Index: 1.4252
• Boiling Point: 67.2°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 0.831g/cm³
• LogP: 1.97250

Purity/Quality:

99.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ISO-PROPENYLCYCLOPROPANE

There total 6 articles about ISO-PROPENYLCYCLOPROPANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,2'-dicyclopropyl-2,2'-azopropane (17396-98-4) + thiophenol (108-98-5) → 2-methyl-2-pentene (625-27-4) + 2-cyclopropylpropane (3638-35-5) + isopropenylcyclopropane (4663-22-3) + 2,3-dicyclopropyl-2,3-dimethylbutane + ((E)-2-Methyl-pent-2-enylsulfanyl)-benzene + ((E)-2-Methyl-pent-2-enylsulfanyl)-benzene

Guidance literature:

In fluorobenzene; at 22 ℃; Product distribution; Irradiation;

DOI:10.1021/jo961685h

Reference yield:

tert-Butyl 3-(tert-butylazo)-3-cyclopropylperbutanoate → Isobutane (75-28-5,40921-86-6) + carbon dioxide (124-38-9,18923-20-1) + isopropenylcyclopropane (4663-22-3) + Methyl 3-cyclopropylbutanoate + tert-Butyl 3-cyclopropyl-2-perbutenoate (156423-37-9) + isobutene (115-11-7,15220-85-6)

Guidance literature:

In fluorobenzene; at 25 ℃; Product distribution; Irradiation; also with various amount of 1,4-cyclohexadiene;

DOI:10.1021/jo00093a031

Reference yield:

methanol (67-56-1) + <1-(1-Methylethyl)cyclopropyl>nitrosocarbamidsaeure-methylester (104131-89-7) → isopropylidenecyclopropane (4741-86-0) + isopropenylcyclopropane (4663-22-3) + (1-Methoxy-1-methylethyl)cyclopropan (104131-96-6) + 1-(1-Methylethyl)-1-methoxycyclopropan (104131-95-5) + 2-(Methoxymethyl)-3-methyl-1-buten (104131-94-4)

Guidance literature:

With potassium carbonate; Mechanism; Product distribution;

upstream raw materials:

2-cyclopropyl-2-propanol

methanol

<1-(1-Methylethyl)cyclopropyl>nitrosocarbamidsaeure-methylester

2,2'-dicyclopropyl-2,2'-azopropane

Downstream raw materials:

2,2-dimethyltetrahydrofuran

Cyclopropyl methyl ketone

2-Methylpentane

2-cyclopropyl-1-(phenylthio)propane

Refernces

• 1、 Engel, Paul S.,Wu, Aiyin. "Photolysis of β-Azo Perester, a Bifunctional Initiator. The Fragmentation Rate of a β-Peroxy Ester Radical Determined by the Cyclopropylcarbinyl Clock Method". . p. 3969 - 3974. Retrieved 2007/10/02.