Cobalt(II) phthalocyanine

Base Information

• Chemical Name: Cobalt(II) phthalocyanine
• CAS No.: 3317-67-7
• Molecular Formula: C32H16CoN8
• Molecular Weight: 571.526
• Hs Code.: DERIVATION
• European Community (EC) Number: 222-012-7
• Mol file: 3317-67-7.mol

Synonyms:cobalt phthalocyanine

Chemical Property of Cobalt(II) phthalocyanine

Chemical Property:

• Appearance/Colour: purple powder
• Melting Point: >300 °C
• PSA: 69.16000
• Density: 1.56 g/cm³
• LogP: 2.61600
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 571.082986
• Heavy Atom Count: 41
• Complexity: 1080

Purity/Quality:

98% ^*data from raw suppliers

CobaltPhthalocyanine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 40
• Safety Statements: 36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Dyes -> Phthalocyanine Dyes
• Canonical SMILES: C1=CC=C2C(=C1)C3=NC4=NC(=NC5=C6C=CC=CC6=C([N-]5)N=C7C8=CC=CC=C8C(=N7)N=C2[N-]3)C9=CC=CC=C94.[Co+2]
• Description: Cobalt phthalocynine (CoPc) is a member of metal phthalocyanines (MPcs) are frequently used in many?organic electronic devices such as light-emitting diodes (LEDs), organic photovoltaics (OPVs), organic field-effect transistors (OFETs) and chemical sensors ?as a p-type semiconducting material. Compared to other?hole-injection layer (HIL) materials, most metal phthalocyanines are water and air stable, thermally stable, and nontoxic.?They can be sublimed or sputtered with highly uniform, thin films on a variety of substrates. The synthesis of such materials are also relatively inexpensive and easy to prepare. The chemical structure of MPc allows tuning of its ionisation potential or?HOMO levels by altering the central atom in Pc macrocycles.
• Uses: Cobalt(II) phthalocyanine may be used to develop carbon black based electrocatalysts. CoPC may be used as an end capping agent of a hyperbranched poly(aryl ether ketone) to be used for oxidative decomposition of 2,4,6,-trichlorophenol. CoPC modified carbon paste may be used as indicators for electrocatalytic amperometric measurements. ZnO impregnated with CoPC may be used as a sensitizer to determine the photodegradation of cyanide in aqueous suspension. CoPC catalyzed aerobic regenerations of aldehydes and ketones have been investigated.

Technology Process of Cobalt(II) phthalocyanine

There total 77 articles about Cobalt(II) phthalocyanine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

cobalt(II) diacetate tetrahydrate (6147-53-1) + 29H,31H-Phthalocyanine (574-93-6) → cobalt(II) phthalocyanine (3317-67-7)

Guidance literature:

With butyl(2-hydroxyethyl)dimethylammonium acetate; at 100 ℃; Ionic liquid; Inert atmosphere;

DOI:10.1080/00397911.2013.867505

Reference yield: 92.0%

cobalt(II) chloride hexahydrate + urea (57-13-6) + phthalonitrile (91-15-6) → cobalt(II) phthalocyanine (3317-67-7)

Guidance literature:

With ammonium molybdate; at 110 ℃; for 0.166667h; Microwave irradiation;

DOI:10.1142/S1088424612501106

Reference yield: 92.0%

phthalimide (136918-14-4,85-41-6) + cobalt(II) chloride hexahydrate + urea (57-13-6) → cobalt(II) phthalocyanine (3317-67-7)

Guidance literature:

With ammonium molybdate; at 120 ℃; for 0.166667h; Microwave irradiation;

DOI:10.1142/S1088424612501106

upstream raw materials:

phthalic anhydride

phthalonitrile

phthalimide

nitrobenzene

Downstream raw materials:

29H,31H-phthalocyanine

water

cobalt(II)

[μ-(1,4-diazabicyclo[2.2.2]octane)(phthalocyaninato)cobalt(II)*1.1 dichlorobenzene](n)

Refernces

• 1、 Orihashi, Yuji,Nishikawa, Michinori,Ohno, Hiroyuki,Tsuchida, Eishun,Matsuda, Hiro,et al.. "Effect of Substituents on the Oxidation Potential of Phthalocyanines and Electrocrystallization". . p. 3731 - 3738. Retrieved 1987.
• 2、 Liou, Kwangkyoung,Jacobsen, Claus S.,Hoffman, Brian M.. "Two-Channel Conductivity and Carrier Crossover in CoxNi1-x(pc)I, Alloys of the Molecular Conductors (Phthalocyaninato)nickel Iodide and (Phthalocyaninato)cobalt Iodide". . p. 6616 - 6620. Retrieved 1989.
• 3、 Mercati, Giorgio,Morazzoni, Franca,Barzaghi, Mario,Carniti, Paolo,Ragaini, Vittorio,Campadelli, Fabio. "". . . Retrieved 1979.
• 4、 Galezowski, Wlodzimierz,Kubicki, Maciej. "X-ray structures and homolysis of some alkylcobalt(III) phthalocyanine complexes". . p. 9902 - 9913. Retrieved 2005.
• 5、 Mazur, Ursula,Leonetti, Maya,English, William A.,Hipps. "Spontaneous solution-phase redox deposition of a dense cobalt(II) phthalocyanine monolayer on gold". . p. 17003 - 17006. Retrieved 2004.
• 6、 Xu, Zhanwei,Li, Hejun,Li, Wei,Cao, Gaoxiang,Zhang, Qinglin,Li, Kezhi,Fu, Qiangang,Wang, Jie. "Large-scale production of graphene by microwave synthesis and rapid cooling". . p. 1166 - 1168. Retrieved 2011.
• 7、 Tan, Amin,Tian, Min,Yang, Yan,Zhang, Gai,Zhang, Yufan. "Effects of MN4-Type Coordination Structure in Metallophthalocyanine for Bio-Inspired Oxidative Desulfurization Performance". . . Retrieved 2022/02/14.
• 8、 Jain, Suman L.,Krishnamurty, Sailaja,Ray, Anjan,Saini, Sandhya,Samal, Pragnya Paramita. "An innovative light assisted production of acetic acid from CO2and methanol: A first photocatalytic approach using a reusable cobalt(ii) molecular hybrid at atmospheric pressure". supporting information. p. 9048 - 9060. Retrieved 2021/11/30.