2-AMINOANTHRACENE

Base Information

• Chemical Name: 2-AMINOANTHRACENE
• CAS No.: 613-13-8
• Molecular Formula: C14H11 N
• Molecular Weight: 193.248
• Hs Code.: 2921499090
• European Community (EC) Number: 210-330-9
• NSC Number: 400535
• UNII: 8240818JGU
• DSSTox Substance ID: DTXSID2024458
• Nikkaji Number: J3.650A
• Wikidata: Q26841182
• Metabolomics Workbench ID: 54954
• ChEMBL ID: CHEMBL83154
• Mol file: 613-13-8.mol

Synonyms:2-Anthramine(6CI,7CI,8CI); 2-Aminoanthracene; 2-Anthracylamine; 2-Anthrylamine; NSC 400535;b-Aminoanthracene

Chemical Property of 2-AMINOANTHRACENE

Chemical Property:

• Appearance/Colour: yellow powder
• Vapor Pressure: 4.52E-07mmHg at 25°C
• Melting Point: 238-241 °C(lit.)
• Refractive Index: 1.5850 (estimate)
• Boiling Point: Vapour density:
• PKA: 4.32±0.30(Predicted)
• Flash Point: 229°C
• PSA: 26.02000
• Density: 1.208g/cm³
• LogP: 4.15640
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Solubility.: Chloroform (Very Slightly), Dichloromethane (Slightly), DMSO (Slightly)
• Water Solubility.: 1.3mg/L(24 oC)
• XLogP3: 3.5
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 193.089149355
• Heavy Atom Count: 15
• Complexity: 225

Purity/Quality:

99% ^*data from raw suppliers

2-Aminoanthracene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Polycyclic Aromatic Hydrocarbons
• Canonical SMILES: C1=CC=C2C=C3C=C(C=CC3=CC2=C1)N
• Uses: 2-Aminoanthracene can be used as a reactant to prepare: Steroid derived naphthoquinoline asphaltene compounds via multicomponent cyclocondensation reaction with 5-α-cholestan-3-one and aromatic aldehydes. Naphtho[2,3- f ]quinoline derivatives by reacting with aromatic aldehyde and acetone or acetophenone catalyzed by iodine.

Technology Process of 2-AMINOANTHRACENE

There total 18 articles about 2-AMINOANTHRACENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

2-aminoanthraquinone (117-79-3) → 2-aminoanthracene (613-13-8)

Guidance literature:

2-aminoanthraquinone; With sodium hydroxide; zinc; Reflux;

With hydrogenchloride; In water;

DOI:10.1016/j.tetlet.2013.02.085

Reference yield: 61.0%

2-azido-anthracene (58399-84-1) → 2-aminoanthracene (613-13-8)

Guidance literature:

In tetrahydrofuran; water; at 20 ℃; for 2h;

DOI:10.1016/j.jphotochem.2018.11.011

Reference yield: 49.0%

9-bromo-2-aminoanthracene (1186505-24-7) + phosphonic acid diethyl ester (762-04-9) → diethyl 2-amino-9-anthrylphosphonate (1186505-25-8) + 2-aminoanthracene (613-13-8)

Guidance literature:

With N-Methyldicyclohexylamine; palladium diacetate; triphenylphosphine; In ethanol; for 48h; Reflux; Inert atmosphere;

DOI:10.1246/cl.2009.738

upstream raw materials:

acetamide

2-hydroxyanthracene

2-aminoanthraquinone

methanol

Downstream raw materials:

1-phenylazo-[2]anthrylamine

Naphtho<2,3-f>chinolin

Anthracen-2-yl-carbamic acid 2-nitro-benzyl ester

17-(4-tolyl)-8,17-dihydrodinaphtho[2,3-a:2',3'-j]acridine

Refernces

• 1、 Biswas, Bidisha,Venkateswarulu,Gaur, Pankaj,Sharma, Yamini,Sinha, Sougata,Ghosh, Subrata. "Triggered emission for rapid detection of hydrogen sulfide chaperoned by large Stokes shift". . p. 264 - 270. Retrieved 2019.
• 2、 Guan, Weiming,Wang, Gengxin,Ding, Jingbo,Li, Bao,Wu, Lixin. "A supramolecular approach of modified polyoxometalate polymerization and visualization of a single polymer chain". . p. 10788 - 10791. Retrieved 2019.
• 3、 Agbowuro, Ayodeji A.,Anifowose, Abiodun,Lu, Wen,Tan, Chalet,Tripathi, Ravi,Wang, Binghe,Yang, Xiaoxiao. "Inducing apoptosis through upregulation of p53: structure–activity exploration of anthraquinone analogs". . p. 1199 - 1210. Retrieved 2020/06/17.