Acetamiprid

Base Information

• Chemical Name: Acetamiprid
• CAS No.: 135410-20-7
• Molecular Formula: C10H11ClN4
• Molecular Weight: 222.677
• Hs Code.: 29333990
• Mol file: 135410-20-7.mol

Synonyms:Ethanimidamide,N-[(6-chloro-3-pyridinyl)- methyl]-N'-cyano-N-methyl-,(1E)-;(E)-N-(6-Chloro-3-pyridyl)methyl-N-cyano-N-methylacetamidine;(1E)-N-[(6-Chloro-3-pyridinyl) methyl]-N'-cyano-N-methylethanimidamide;Acetamiprid,Burofezin,Bifenthrin,Cyfluthrin,carbofuran,Chlorpyrifos;Acetamiprid 20%SL;

Chemical Property of Acetamiprid

Chemical Property:

• Appearance/Colour: white powder
• Vapor Pressure: 3.85E-05mmHg at 25°C
• Melting Point: 101-103 ºC
• Refractive Index: 1.57
• Boiling Point: 352.4 ºC at 760 mmHg
• PKA: -0.44±0.10(Predicted)
• Flash Point: 166.9 ºC
• PSA: 52.28000
• Density: 1.17 g/cm³
• LogP: 2.06628
• Storage Temp.: 0-6°C
• Water Solubility.: 4200ml/L

Purity/Quality:

95%TC ^*data from raw suppliers

Acetamiprid ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 23/25-57-52/53
• Safety Statements: 45-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: 1. Acetamiprid belongs to the same series with imidacloprid. But its nsecticidal spectruma is broader than imidacloprid. It mainly has a better effect on cucumbers aphids, apples aphids, citrus aphids and tobacco aphids. Since the mechanism of acetamiprid is unique, it have a good effect on pests that can cause resistance to organophosphorus, carbamates and pyrethroids pesticides. 2. Efficient, broad-spectrum chlorinated insecticides. A novel neonicotinid insecticide against Holotrichia consanguinea in sugarcane. Reports show that when exposed to neonicotinid pesticides honeybees have probelms returnign home after foraging and bumb lebee colonies grow poorly and produce fewer queens. Acetamiprid is a systemic insecticide for soil and foliar application. It is used to control Hemiptera, especially aphids, Thysanoptera and Lepidoptera on a wide range of crops, especially vegetables, fruit and tea.

Technology Process of Acetamiprid

There total 2 articles about Acetamiprid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.6%

ethyl N-cyanoacetoimidate (1558-82-3) + 1-(6-chloropyridin-3-yl)-N-methylmethanamine (120739-62-0) → acetamiprid (135410-20-7)

Guidance literature:

In ethanol; at 65 ℃;

Reference yield:

→ acetamiprid (135410-20-7)

Guidance literature:

Reference yield:

acetamiprid (135410-20-7) → 6-Chloro-3-pyridinecarboxylic acid (5326-23-8)

Guidance literature:

With Er doped Ti/SnO₂-Sb electrode; for 3h; Kinetics; Electrochemical reaction;

DOI:10.1039/c5ra09376g

upstream raw materials:

ethyl N-cyanoacetoimidate

1-(6-chloropyridin-3-yl)-N-methylmethanamine

Downstream raw materials:

acetamiprid N-desmethyl

C₇H₆O₃*C₁₀H₁₁ClN₄

6-Chloro-3-pyridinecarboxylic acid

Refernces

• 1、 -. "Preparation method of acetamiprid". Paragraph 0015. . Retrieved 2017/02/23.
• 2、 -. "Method for exterminating termites". . . Retrieved 2008/06/13.