methyl 9-(oxiran-2-yl)nonanoate

Base Information

• Chemical Name: methyl 9-(oxiran-2-yl)nonanoate
• CAS No.: 22663-09-8
• Molecular Formula: C12H22 O3
• Molecular Weight: 214.305
• Mol file: 22663-09-8.mol

Synonyms:Oxiranenonanoicacid, methyl ester (9CI); Undecanoic acid, 10,11-epoxy-, methyl ester(6CI,7CI,8CI); Methyl 10,11-epoxyundecanoate; Methyl 10-epoxyundecenoate; NSC93956

Chemical Property of methyl 9-(oxiran-2-yl)nonanoate

Chemical Property:

• Vapor Pressure: 0.00435mmHg at 25°C
• Boiling Point: 278.1°Cat760mmHg
• Flash Point: 113.2°C
• Density: 0.985g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methyl 9-(oxiran-2-yl)nonanoate

There total 5 articles about methyl 9-(oxiran-2-yl)nonanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

Methyl 10-undecenoate (111-81-9) → methyl 9-(oxiran-2-yl)nonanoate (22663-09-8)

Guidance literature:

With Oxone; ethylene diamine tetraacetic acid tetrasodium salt; sodium hydrogencarbonate; In acetonitrile; at 0 ℃; for 1h;

DOI:10.1021/ja051759j

Reference yield: 96.0%

methyl 10-hydroxy-11-iodoundecanoic acid (91258-67-2) → methyl 9-(oxiran-2-yl)nonanoate (22663-09-8)

Guidance literature:

With Al₂O₃-Na₂CO₃ catalyst; at 40 - 45 ℃; for 0.0166667h; Microwave irradiation;

DOI:10.1080/00397911.2010.539755

Reference yield:

d,l-2-ethylhexanal (123-05-7) + Methyl 10-undecenoate (111-81-9) → heptan-3-ol (589-82-2) + 2-Ethylhexanoic acid (149-57-5) + heptan-3-yl formate (54009-71-1) + methyl 9-(oxiran-2-yl)nonanoate (22663-09-8) + heptan-3-one (106-35-4)

Guidance literature:

With oxygen; at 60 ℃; for 11h; Temperature;

DOI:10.1021/op980075b

upstream raw materials:

peracetic acid

Methyl 10-undecenoate

methyl 10-hydroxy-11-iodoundecanoic acid

d,l-2-ethylhexanal

Downstream raw materials:

Methyl 10-undecenoate

10,11-epoxyundecan-1-ol

undecane-1,10-diol

undecane-1,11-diol

Refernces

• 1、 Martínez, Javier,de la Cruz-Martínez, Felipe,Martínez de Sarasa Buchaca, Marc,Fernández-Baeza, Juan,Sánchez-Barba, Luis F.,North, Michael,Castro-Osma, José A.,Lara-Sánchez, Agustín. "Efficient Synthesis of Cyclic Carbonates from Unsaturated Acids and Carbon Dioxide and their Application in the Synthesis of Biobased Polyurethanes". . p. 460 - 468. Retrieved 2021/04/06.
• 2、 Reddy, G. Sudhakar,Padhi, Birakishore,Bharath, Yada,Mohapatra, Debendra K.. "Total Synthesis of Four Isomers of the Proposed Structures of Cryptorigidifoliol K". supporting information. p. 6506 - 6509. Retrieved 2017/12/26.