Propane, 2-(ethenyloxy)-

Base Information

• Chemical Name: Propane, 2-(ethenyloxy)-
• CAS No.: 926-65-8
• Molecular Formula: C5H10O
• Molecular Weight: 86.1338
• Hs Code.: 2909199090
• European Community (EC) Number: 213-142-5
• DSSTox Substance ID: DTXSID0061292
• Nikkaji Number: J102.079J
• Wikidata: Q22027973
• Mol file: 926-65-8.mol

Synonyms:926-65-8;ISOPROPYL VINYL ETHER;Vinyl isopropyl ether;Propane, 2-(ethenyloxy)-;2-ethenoxypropane;2-(Vinyloxy)propane;2-(Ethenyloxy)propane;Isopropylvinylether;Ether, isopropyl vinyl;EINECS 213-142-5;2-vinyloxypropane;Isopropy Vinyl Ether;Isopropoxyethene;Isopropoxyethylene;1-Isopropoxyethylene;2-(ethenyloxy)-propane;Propano, 2-(eteniloxi)-;CH2=CHOCH(CH3)2;DTXSID0061292;GNUGVECARVKIPH-UHFFFAOYSA-;MFCD00053718;AKOS006274610;4,4-(1,14-Tetradecanediyl)dioxydianiline;FT-0633104;EN300-133045;A844305;Q22027973

Chemical Property of Propane, 2-(ethenyloxy)-

Chemical Property:

• Appearance/Colour: colorless and transparent liquid
• Vapor Pressure: 230mmHg at 25°C
• Melting Point: -140oC
• Refractive Index: 1.388
• Boiling Point: 57.5 °C at 760 mmHg
• Flash Point: °C
• PSA: 9.23000
• Density: 0.762 g/cm³
• LogP: 1.55490
• XLogP3: 1.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 86.073164938
• Heavy Atom Count: 6
• Complexity: 39.2

Purity/Quality:

99% ^*data from raw suppliers

ISOPROPYL VINYL ETHER 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)OC=C

Technology Process of Propane, 2-(ethenyloxy)-

There total 11 articles about Propane, 2-(ethenyloxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

isopropyl alcohol (67-63-0,8013-70-5) + acetylene (74-86-2,25067-58-7) → vinyl isopropyl ether (926-65-8)

Guidance literature:

With sodium hydroxide; cesium fluoride; In dimethyl sulfoxide; at 100 ℃; for 5.5h; atmospheric pressure;

DOI:10.1007/s11178-005-0222-y

Reference yield: 65.0%

β-isopropoxyethyl vinyl sulfoxide (80857-63-2) → vinyl isopropyl ether (926-65-8) + ethenesulfenic acid (2492-74-2)

Guidance literature:

With potassium hydroxide; at 280 - 290 ℃;

Reference yield: 62.0%

β-isopropoxyethyl vinyl sulfoxide (80857-63-2) → vinyl isopropyl ether (926-65-8)

Guidance literature:

With potassium hydroxide; at 60 - 70 ℃; for 1h;

upstream raw materials:

1,1-diisopropoxy-ethane

1-chloro-1-(1-methyletoxy)ethane

2-isopropyloxyethyl bromide

-butyl vinyl ether

Downstream raw materials:

1-benzoyloxy-1-isopropoxy-ethane

4-hydroxy-3-(4-methylbenzoyl)-6-(4-methylphenyl)-2H-pyran-2-one

malondialdehyde bis(diethyl acetal)

1,3,3-triethoxy-1-(isopropoxy)propane

Refernces

• 1、 Oparina,Shaikhudinova,Parshina,Vysotskaya,Preiss,Henkelmann,Trofimov. "Nucleophilic addition to acetylenes in superbasic catalytic systems: XIII. Fluoride cesium containing systems, efficient catalysts for alkanols vinylation". . p. 656 - 660. Retrieved 2007/10/03.
• 2、 Bouchoux, Guy,Djazi, Feycal,Hoppilliard, Yannik,Jaudon, Pascale,Nouts, Nathalie. "Dissociation of Positively Charged Aliphatic Epoxides. II. +. Epoxides and α,β Unsaturated Ethers". . p. 33 - 41. Retrieved 2007/10/02.