2-[[(Butylamino)carbonyl]oxy]ethyl acrylate

Base Information

• Chemical Name: 2-[[(Butylamino)carbonyl]oxy]ethyl acrylate
• CAS No.: 63225-53-6
• Deprecated CAS: 639806-06-7,211629-40-2
• Molecular Formula: C10H17NO4
• Molecular Weight: 215.249
• Hs Code.: 2924199090
• European Community (EC) Number: 264-036-0
• UNII: I564J85TRD
• DSSTox Substance ID: DTXSID1069798
• Nikkaji Number: J327.040H
• Wikidata: Q81996842
• Mol file: 63225-53-6.mol

Synonyms:63225-53-6;2-[[(Butylamino)carbonyl]oxy]ethyl acrylate;2-(butylcarbamoyloxy)ethyl prop-2-enoate;2-Propenoic acid, 2-[[(butylamino)carbonyl]oxy]ethyl ester;2-ACRYLOYLOXYETHYL BUTYLCARBAMATE;I564J85TRD;2-Propenoic acid, 2-(((butylamino)carbonyl)oxy)ethyl ester;EINECS 264-036-0;2-(((Butylamino)carbonyl)oxy)ethyl acrylate;GENOMER 122;UNII-I564J85TRD;EBECRYL 1029;SCHEMBL301355;DTXSID1069798;MFCD02093631;EM-2080;2-(((butylamino)carbonyl)-oxy)ethyl acrylate;Acrylic acid 2-(butylcarbamoyloxy)ethyl ester;1-butane carbamic acid 2-acryloyloxyethyl ester;2-[(BUTYLCARBAMOYL)OXY]ETHYL PROP-2-ENOATE;W-111220;2-(((BUTYLAMINO)CARBONYL)OXY)ETHYL 2-PROPENOATE

Chemical Property of 2-[[(Butylamino)carbonyl]oxy]ethyl acrylate

Chemical Property:

• Vapor Pressure: 0.000196mmHg at 25°C
• Refractive Index: n20/D 1.46(lit.)
• Boiling Point: 327.9°C at 760 mmHg
• PKA: 12.49±0.46(Predicted)
• Flash Point: >230 °F
• PSA: 68.12000
• Density: 1.06 g/mL at 25 °C(lit.)
• LogP: 1.44630
• Storage Temp.: 2-8°C
• Water Solubility.: 4.99g/L at 21℃
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 9
• Exact Mass: 215.11575802
• Heavy Atom Count: 15
• Complexity: 216

Purity/Quality:

99.9% ^*data from raw suppliers

2-[[(Butylamino)carbonyl]oxy]ethyl acrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCNC(=O)OCCOC(=O)C=C

Technology Process of 2-[[(Butylamino)carbonyl]oxy]ethyl acrylate

There total 5 articles about 2-[[(Butylamino)carbonyl]oxy]ethyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-hydroxyethyl N-butylcarbamate (13105-54-9) + acrylic acid (79-10-7) → acrylic acid 2-butylcarbamoyloxy-ethyl ester (63225-53-6)

Guidance literature:

With hypophosphorous acid; 4-methoxy-phenol; toluene-4-sulfonic acid; In toluene; at 70 ℃; for 6h; Reduced pressure;

Reference yield:

2-hydroxyethyl N-butylcarbamate (13105-54-9) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → acrylic acid 2-butylcarbamoyloxy-ethyl ester (63225-53-6)

Guidance literature:

With phenothiazine; 2,6-di-tert-butyl-4-methyl-phenol; titanium(IV) isopropylate; tetrabutoxytitanium; at 65 ℃; for 10.5h;

Reference yield:

[1,3]-dioxolan-2-one (96-49-1) + N-butylamine (109-73-9,85404-21-3) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → acrylic acid 2-butylcarbamoyloxy-ethyl ester (63225-53-6)

Guidance literature:

novozyme 435; at 60 ℃; for 24h; Enzymatic reaction;

upstream raw materials:

n-butyl isocyanide

2-hydroxyethyl acrylate

2-hydroxyethyl N-butylcarbamate

acrylic acid

Refernces

• 1、 -. "PROCESS FOR PRODUCING CARBAMOYLOXY (METH)ACRYLATES AND NEW CARBAMOYLOXY (METH)ACRYLATES". Page 35-36. . Retrieved 2008/06/13.