1,2-Diazidoethane

Base Information

• Chemical Name: 1,2-Diazidoethane
• CAS No.: 629-13-0
• Molecular Formula: C2H4 N6
• Molecular Weight: 112.094
• DSSTox Substance ID: DTXSID70212072
• Nikkaji Number: J83.981G
• Wikidata: Q83087109
• Mol file: 629-13-0.mol

Synonyms:1,2-DIAZIDOETHANE;629-13-0;Azide-C2-Azide;Ethane, 1,2-diazido-;1,2-Diazidoethane [Forbidden];Ethylenediazide;Discontnued (Explosive);Discontnued (Explosive)"";C2H4N6;YSZC1981;SCHEMBL13510789;DTXSID70212072;AKOS006279885;HY-138535;CS-0148650;FT-0666425;D84711;EN300-216151

Chemical Property of 1,2-Diazidoethane

Chemical Property:

• Boiling Point: 199.99°C (rough estimate)
• PSA: 99.50000
• Density: 1.3208 (rough estimate)
• LogP: 0.51252
• XLogP3: 2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 3
• Exact Mass: 112.04974415
• Heavy Atom Count: 8
• Complexity: 119

Purity/Quality:

99%+, ^*data from raw suppliers

1,2-Diazidoethane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(CN=[N+]=[N-])N=[N+]=[N-]

Technology Process of 1,2-Diazidoethane

There total 2 articles about 1,2-Diazidoethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

ethylene dibromide (106-93-4) → 1,2-diazidoethane (629-13-0)

Guidance literature:

With sodium azide; In water; at 80 ℃; for 24h;

DOI:10.1002/ejoc.201201201

Reference yield: 71.2%

1,2-dichloro-ethane (107-06-2,52399-93-6) → 1,2-diazidoethane (629-13-0)

Guidance literature:

With sodium azide; In N,N-dimethyl-formamide; for 20h; Heating;

Reference yield: 96.0%

1,2-diazidoethane (629-13-0) + C15H18O2 → C32H40N6O4

Guidance literature:

With triethylamine; In tetrahydrofuran;

DOI:10.1016/j.molstruc.2021.131858

upstream raw materials:

1,2-dichloro-ethane

ethylene dibromide

Downstream raw materials:

1,2-bis-(N'-phenyl-triazenyl)-ethane

ethylenediamine

1,2-bis(4-benzoyl-1,2,3-triazol-1-yl)ethane

C₃₈H₃₈N₈O₃

Refernces

• 1、 Kiran,Sarasija,Rao,Jeyanthi,Rao,Ashok. "Synthesis, Antioxidant, and Antimicrobial Activities of Novel Bis-Aroylbenzofuran Fused 1,2,3-Triazoles Bearing Alkane Spacers". . p. 2410 - 2419. Retrieved 2019/01/04.
• 2、 Swetha,Ramana, P. Venkata,Shirodkar. "Simple and efficient method for the synthesis of azides in water-THF solvent system". experimental part. p. 348 - 353. Retrieved 2011/10/02.