2-(P-CHLOROPHENYL)-4,6-DIPHENYL-S-TRIAZINE

Base Information

• Chemical Name: 2-(P-CHLOROPHENYL)-4,6-DIPHENYL-S-TRIAZINE
• CAS No.: 3114-52-1
• Molecular Formula: C21H14 Cl N3
• Molecular Weight: 343.815
• Mol file: 3114-52-1.mol

Synonyms:s-Triazine,2-(p-chlorophenyl)-4,6-diphenyl- (7CI,8CI)

Chemical Property of 2-(P-CHLOROPHENYL)-4,6-DIPHENYL-S-TRIAZINE

Chemical Property:

• Vapor Pressure: 4.87E-12mmHg at 25°C
• Boiling Point: 561°Cat760mmHg
• PKA: 0.45±0.10(Predicted)
• Flash Point: 322.5°C
• PSA: 38.67000
• Density: 1.241g/cm³
• LogP: 5.52600

Purity/Quality:

99.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-(P-CHLOROPHENYL)-4,6-DIPHENYL-S-TRIAZINE

There total 15 articles about 2-(P-CHLOROPHENYL)-4,6-DIPHENYL-S-TRIAZINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

benzamidin (618-39-3) + para-Chlorobenzyl alcohol (873-76-7) → 2-(4-chlorophenyl)-4,6-diphenyl-1,3,5-triazine (3114-52-1)

Guidance literature:

With oxygen; In toluene; at 110 ℃; for 20h; Schlenk technique;

DOI:10.1016/j.catcom.2019.05.005

Reference yield: 92.0%

2-chloro-4,6-diphenyl-1,3,5-triazine (3842-55-5) + 4-Chlorophenylboronic acid (1679-18-1) → 2-(4-chlorophenyl)-4,6-diphenyl-1,3,5-triazine (3114-52-1)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In tetrahydrofuran; water; at 80 ℃; for 18h; Inert atmosphere;

Reference yield: 89.0%

benzamidine monohydrochloride (1670-14-0) + para-chloroacetophenone (99-91-2) → 2-(4-chlorophenyl)-4,6-diphenyl-1,3,5-triazine (3114-52-1)

Guidance literature:

With iodine; caesium carbonate; In dimethyl sulfoxide; at 20 - 110 ℃; for 16.0833h; regioselective reaction;

DOI:10.1021/acs.joc.7b02313

upstream raw materials:

2-(4-chlorophenyl)-4,5-diphenyl-1H-imidazole

phenylboronic acid

2-chloro-4,6-diphenyl-1,3,5-triazine

4-Chlorophenylboronic acid

Downstream raw materials:

C₅₁H₃₃N₅

2,4-diphenyl-6-(4-(4_,4_',5,5'-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-1,3,5-triazine

Refernces

• 1、 -. "COMPOUND FOR ORGANIC OPTOELECTRONIC DEVICE, COMPOSITION FOR ORGANIC OPTOELECTRONIC DEVICE, ORGANIC OPTOELECTRONIC DEVICE, AND DISPLAY DEVICE". Paragraph 0219; 0222-0223. . Retrieved 2021/09/03.
• 2、 -. "COMPOSITION FOR OPTOELECTRONIC DEVICE AND ORGANIC OPTOELECTRONIC DEVICE AND DISPLAY DEVICE". Paragraph 0355-0356. . Retrieved 2020/08/30.