1,1'-Diphenyl-1,1'-bicyclopentyl

Base Information

• Chemical Name: 1,1'-Diphenyl-1,1'-bicyclopentyl
• CAS No.: 59358-70-2
• Molecular Formula: C22H26
• Molecular Weight: 290.4418
• DSSTox Substance ID: DTXSID00208100
• Nikkaji Number: J1.698.795F
• Wikidata: Q83082191
• Mol file: 59358-70-2.mol

Synonyms:1,1'-Diphenyl-1,1'-bicyclopentyl;59358-70-2;DTXSID00208100;Benzene, 1,1'-[1,1'-bicyclopentyl]-1,1'-diylbis-

Chemical Property of 1,1'-Diphenyl-1,1'-bicyclopentyl

Chemical Property:

• Boiling Point: 396.6°Cat760mmHg
• Flash Point: 212.9°C
• Density: 1.051g/cm³
• XLogP3: 7.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 290.203450829
• Heavy Atom Count: 22
• Complexity: 308

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1CCC(C1)(C2=CC=CC=C2)C3(CCCC3)C4=CC=CC=C4

Technology Process of 1,1'-Diphenyl-1,1'-bicyclopentyl

There total 10 articles about 1,1'-Diphenyl-1,1'-bicyclopentyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

1-phenyl-1-cyclopentanecarboxylic acid (77-55-4) → 1,1'-Diphenyl-1,1'-bicyclopentyl (59358-70-2)

Guidance literature:

With C₄₄H₃₂N₄⁽²⁺⁾*2F₆P^(1-); sodium hydroxide; In water; acetonitrile; at 20 ℃; for 18h; Irradiation;

DOI:10.1039/d0sc03958f

Reference yield: 60.0%

4-(1-phenyl-cyclopentanecarbonyl)-benzonitrile (377771-60-3) → 1,1'-Diphenyl-1,1'-bicyclopentyl (59358-70-2)

Guidance literature:

In acetonitrile; at 20 ℃; for 5.5h; Photolysis;

DOI:10.1021/ol0165995

Reference yield: 47.0%

4-(1-phenyl-cyclopentanecarbonyl)-benzoic acid methyl ester → 1,1'-Diphenyl-1,1'-bicyclopentyl (59358-70-2)

Guidance literature:

In acetonitrile; at 20 ℃; for 3h; Photolysis;

DOI:10.1021/ol0165995

upstream raw materials:

1-ethoxycarbonyl-1-phenylcyclopentane

1-phenylcyclopentanol

1-phenyl-1-cyclopentanecarbonitrile

toluene

Downstream raw materials:

cyclopentylbenzene

cyclopent-1-en-1-ylbenzene

Refernces

• 1、 Kang, Ting,Scheffer, John R.. "An unexpected Paterno-Buechi reaction in the crystalline state". . p. 3361 - 3364. Retrieved 2007/10/03.