10-(Diphenylmethylene)anthracen-9(10H)-one

Base Information

• Chemical Name: 10-(Diphenylmethylene)anthracen-9(10H)-one
• CAS No.: 667-91-4
• Molecular Formula: C27H18 O
• Molecular Weight: 358.439
• Hs Code.: 29143900
• European Community (EC) Number: 211-570-7
• NSC Number: 89267
• DSSTox Substance ID: DTXSID20216848
• Nikkaji Number: J205.965G
• Wikidata: Q83093164
• Mol file: 667-91-4.mol

Synonyms:9-Benzhydrylidene-10-anthrone;667-91-4;10-(Diphenylmethylene)anthracen-9(10H)-one;10-benzhydrylideneanthracen-9-one;EINECS 211-570-7;Anthrafuchson;NSC89267;Diphenylmethylenanthron;SCHEMBL8653739;C27H18O;DTXSID20216848;C27-H18-O;MFCD00019172;NSC 89267;NSC-89267;9-(Diphenylmethylene)-10(9H)-anthracenone;FT-0632773;10-(Diphenylmethylene)-9(10H)-anthracenone #;9(10H)-Anthracenone, 10-(diphenylmethylene)-;A835546

Chemical Property of 10-(Diphenylmethylene)anthracen-9(10H)-one

Chemical Property:

• Vapor Pressure: 1.58E-09mmHg at 25°C
• Melting Point: 203-207 °C
• Refractive Index: 1.6380 (estimate)
• Boiling Point: 484.1°C at 760 mmHg
• Flash Point: 209.5°C
• PSA: 17.07000
• Density: 1.207g/cm³
• LogP: 6.23840
• XLogP3: 6.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 358.135765193
• Heavy Atom Count: 28
• Complexity: 541

Purity/Quality:

99% ^*data from raw suppliers

9-BENZHYDRYLIDENE-10-ANTHRONE 95.00% ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(=C2C3=CC=CC=C3C(=O)C4=CC=CC=C42)C5=CC=CC=C5

Technology Process of 10-(Diphenylmethylene)anthracen-9(10H)-one

There total 5 articles about 10-(Diphenylmethylene)anthracen-9(10H)-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

3,3'-Diphenyl-10-oxo-spiro-<9-(9,10-dihydroanthracen):l'-(2'-thiiran)> (33977-55-8) → 10-benzhydrylidene-9-anthrone (667-91-4)

Guidance literature:

With triphenylphosphine; In toluene; for 24h; Inert atmosphere; Reflux;

DOI:10.1021/jo101701k

Reference yield:

10-diazo-10H-anthracen-9-one (1705-82-4) + Thiobenzophenon (1450-31-3) → 10-benzhydrylidene-9-anthrone (667-91-4)

Guidance literature:

10-diazo-10H-anthracen-9-one; Thiobenzophenon; In tetrahydrofuran; for 15h; Inert atmosphere;

With triphenylphosphine; In toluene; for 24h; Inert atmosphere; Reflux;

DOI:10.1021/jo101701k

Reference yield:

anthracen-9(10H)-one (90-44-8) + Dichlorodiphenylmethane (2051-90-3) → bianthronyl (434-84-4) + 10-benzhydrylidene-9-anthrone (667-91-4)

Guidance literature:

With xylene; Behandeln des Reaktionsproduktes mit Aceton;

upstream raw materials:

anthracen-9(10H)-one

Dichlorodiphenylmethane

3,3'-Diphenyl-10-oxo-spiro-<9-(9,10-dihydroanthracen):l'-(2'-thiiran)>

10-diazo-10H-anthracen-9-one

Downstream raw materials:

13-phenyl-dibenz[a,de]anthracen-8-one

9-(diphenylmethylene)-10-phenyl-10-hydroxy-9,10-dihydroanthracene

1,2-bis-(9,10-dihydro-[9]anthryl)-1,1,2,2-tetraphenyl-ethane

C₂₇H₁₈S

Refernces