Diethylaluminum fluoride

Base Information

• Chemical Name: Diethylaluminum fluoride
• CAS No.: 367-44-2
• Molecular Formula: C4H10 Al F
• Molecular Weight: 104.103
• Mol file: 367-44-2.mol

Synonyms:diethylaluminum fluoride;SCHEMBL151216;DIETHYL ALUMINUM FLUORIDE;HRXSKIOIHQEGAI-UHFFFAOYSA-M

Chemical Property of Diethylaluminum fluoride

Chemical Property:

• Vapor Pressure: 28500mmHg at 25°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.36800
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 104.0581919
• Heavy Atom Count: 6
• Complexity: 11.1

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[Al+]CC.[F-]

Technology Process of Diethylaluminum fluoride

There total 4 articles about Diethylaluminum fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

xenon difluoride (13709-36-9) + triethylaluminum (97-93-8) → diethylaluminum fluoride (367-44-2)

Guidance literature:

In toluene; byproducts: C2H6, C2H4, Xe; ratio organoaluminum comp.:XeF2 = 2:1, 300 K; chromy., elem. anal., gas volumetric anal., potentiometry, chemiluminescence;

DOI:10.1007/BF00952953

Reference yield:

→ diethylaluminum fluoride (367-44-2)

Guidance literature:

With sodium fluoride;

Reference yield:

triethylaluminum (97-93-8) → diethylaluminum fluoride (367-44-2)

Guidance literature:

With aluminum(III) fluoride;

upstream raw materials:

triethylaluminum

xenon difluoride

Refernces