Lutetium chloride [inci]

Base Information

• Chemical Name: Lutetium chloride [inci]
• CAS No.: 10099-66-8
• Molecular Formula: Cl3Lu
• Molecular Weight: 281.326
• UNII: 2VY5D2E2HC
• Nikkaji Number: J96.307K
• Mol file: 10099-66-8.mol

Synonyms:LUTETIUM CHLORIDE [INCI];AKOS025293956

Chemical Property of Lutetium chloride [inci]

Chemical Property:

• Appearance/Colour: Colorless crystals.
• Melting Point: 905 °C(lit.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 3.98 g/mL at 25 °C(lit.)
• LogP: 2.06850
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 279.84734
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Lu+3]

Technology Process of Lutetium chloride [inci]

There total 15 articles about Lutetium chloride [inci] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

[Lu(chloride)2(water)6]Cl → lutetium(III) chloride (10099-66-8)

Guidance literature:

In neat (no solvent, solid phase); byproducts: H2O; Schlenk techniques; heating Lu compd. under vacuum (1E-3 Torr);

DOI:10.1016/j.poly.2010.02.027

Reference yield: 70.0%

LuCl3(THF)3 (24614-69-5,144491-06-5,120496-88-0) + sodium pentamethylcyclopentadienide → lutetium(III) chloride (10099-66-8) + 2Lu(3+)*C5(CH3)5(1-)*5Cl(1-)*2C4H8O=Lu2(C5(CH3)5)Cl5(C4H8O)2 + {Na(THF)2}Lu(η5-C5Me5)2Cl2 + {Na(THF*OEt2)}{Lu(η5-C5Me5)Cl3} + sodium chloride (7647-14-5)

Guidance literature:

In tetrahydrofuran; all manipulations under Ar or N2; slowly adding NaC5Me5 to refluxing soln. of LuCl3(THF)3 in THF, refluxing (16 h), cooling to room temp.; filtering, evapg. to almost dryness, adding ether, pptn. of desired complex, filtering; (Na(THF)2)Lu(η5-C5Me5)Cl2 and binuclear complex remaining in Et2O soln.;

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + lutetium(III) oxide → lutetium(III) chloride (10099-66-8)

Guidance literature:

In not given; dissol. of Ln oxide in 3 M HCl; evapn.;

DOI:10.1080/00945719708000221

upstream raw materials:

aluminium trichloride

hydrogenchloride

chlorine

lutetium(III) chloride hydrate

Downstream raw materials:

lutetium

lutetium⁽¹⁺⁾

Refernces

• 1、 Neukirch, Michael,Tragl, Sonja,Meyer, H.-Jurgen. "Syntheses and structural properties of rare earth carbodiimides". . p. 8188 - 8193. Retrieved 2006.
• 2、 Janicki, Rafal,Starynowicz, Przemyslaw,Mondry, Anna. "Lanthanide carbonates". . p. 3601 - 3616. Retrieved 2011/10/11.
• 3、 G?adysz-P?aska, Agnieszka,Majdan, Marek,Ferenc, Wies?awa,Sarzyński, Jan. "Comparison of covalency in the lanthanide chloride and nitrate complexes based on the adsorption data on zeolite y". . p. 469 - 474. Retrieved 2012/03/22.