Tribenz[a,c,h]anthracene

Base Information

• Chemical Name: Tribenz[a,c,h]anthracene
• CAS No.: 215-26-9
• Molecular Formula: C26H16
• Molecular Weight: 328.4052
• NSC Number: 30877
• UNII: 7CR6HAE2F2
• DSSTox Substance ID: DTXSID30175831
• Nikkaji Number: J488.488D
• Wikidata: Q83046162
• Mol file: 215-26-9.mol

Synonyms:Tribenz[a,c,h]anthracene;Tribenz(a,C,H)anthracene;Naphtho[1,2-b]triphenylene;7CR6HAE2F2;215-26-9;NSC-30877;NSC30877;dibenzo[f,k]tetraphene;5,6-Tribenzanthracene;Tribenz[a,h]anthracene;UNII-7CR6HAE2F2;1,4:5,6-Tribenzanthracene;DTXSID30175831;GWBFCDHVRQBXAV-UHFFFAOYSA-N;Tribenzo-1,3,4,5,6-anthracene;1,2:3,4:5,6-Tribenzanthracene;NSC 30877;Tribenzo-1,2,3,4,5,6-anthracene;Tribenz(a,c,h)anthracene (8CI)(9CI)

Chemical Property of Tribenz[a,c,h]anthracene

Chemical Property:

• Vapor Pressure: 6.64E-14mmHg at 25°C
• Boiling Point: 604.1°Cat760mmHg
• Flash Point: 314.6°C
• Density: 1.263g/cm³
• XLogP3: 7.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 328.125200510
• Heavy Atom Count: 26
• Complexity: 508

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=CC3=CC4=C(C=C32)C5=CC=CC=C5C6=CC=CC=C64

Technology Process of Tribenz[a,c,h]anthracene

There total 11 articles about Tribenz[a,c,h]anthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

1-Bromonaphthalene (90-11-9) + 1,2-dihydrocyclobutaphenanthren-1-ol (144493-73-2) → 1,2:3,4:5,6-tribenzanthracene (215-26-9)

Guidance literature:

With 2,2,6,6-tetramethylpiperidinyl-lithium; In various solvent(s); for 0.5h; Heating;

DOI:10.1021/jo00052a027

Reference yield: 46.0%

9,16-dihydro-9,16-epoxynaphtho<1,2-b>triphenylene (103202-80-8) → 1,2:3,4:5,6-tribenzanthracene (215-26-9)

Guidance literature:

With diiron nonacarbonyl; In benzene; for 7h; Heating;

DOI:10.1021/jo00366a015

Reference yield: 28.0%

1,2-Bis(triphenylphosphoniomethyl)naphthalin-dibromid (85982-10-1) + 9,10-phenanthrenequinone (84-11-7) → 1,2:3,4:5,6-tribenzanthracene (215-26-9)

Guidance literature:

With lithium hydroxide; In dichloromethane; for 96h; Ambient temperature;

DOI:10.1055/s-1983-30401

upstream raw materials:

(2-methyl-[1]naphthyl)-[9]phenanthryl ketone

1-Bromonaphthalene

1,2-dihydrocyclobutaphenanthren-1-ol

9,16-dihydro-9,16-epoxynaphtho<1,2-b>triphenylene

Refernces

• 1、 Fitzgerald, John J.,Drysdale, Neville E.,Olofson, R. A.. "A Rapid, Convergent, and Regioselective Synthesis of Anthracenes". . p. 7122 - 7126. Retrieved 1992.