Neodymium triacetate

Base Information

• Chemical Name: Neodymium triacetate
• CAS No.: 6192-13-8
• Molecular Formula: C2H4 O2 . 1/3 Nd
• Molecular Weight: 321.374
• Hs Code.: 2915290000
• European Community (EC) Number: 228-244-5
• UNII: 1DH99Q8L73
• DSSTox Substance ID: DTXSID10890616
• Nikkaji Number: J54.954A
• Wikipedia: Neodymium acetate
• Wikidata: Q18211889
• Mol file: 6192-13-8.mol

Synonyms:Neodymium triacetate;6192-13-8;Neodymium acetate;neodymium(3+);triacetate;Neodymacetat [German];Neodymium(3+) acetate;ACETIC ACID, NEODYMIUM(3+) SALT;Neodymacetat;EINECS 228-244-5;Acetic acid, neodymium(3+) salt (3:1);neodymium(III) acetate;NEODYMACETET;neodymium(III)acetate;UNII-1DH99Q8L73;C2H4O2.1/3Nd;Acetic acid, neodymium(3) salt;DTXSID10890616;KETUDCKOKOGBJB-UHFFFAOYSA-K;1DH99Q8L73;C2-H4-O2.1/3Nd;Triacetic acid neodymium(III) salt;Acetic acid,neodymium(3+)salt(3:1);AKOS025295168;Q18211889

Chemical Property of Neodymium triacetate

Chemical Property:

• Appearance/Colour: Light purple
• Boiling Point: 117.1 °C at 760 mmHg
• Flash Point: 40 °C
• PSA: 120.39000
• LogP: -3.73140
• Water Solubility.: 26.2g/100mL H2O [CRC10]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 318.94764
• Heavy Atom Count: 13
• Complexity: 25.5

Purity/Quality:

99.9% ^*data from raw suppliers

Neodymium(III) acetate hydrate (99.9%-Nd) (REO) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Rare Earth Metals
• Canonical SMILES: CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Nd+3]
• Uses: Neodymium Acetate, mainly used for glass, crystal and capacitors. Colours glass delicate shades ranging from pure violet through wine-red and warm gray. Light transmitted through such glass shows unusually sharp absorption bands. It is useful in protective lenses for welding goggles. It is also used in CRT displays to enhance contrast between reds and greens. It is highly valued in glass manufacturing for its attractive purple coloring to glass.

Technology Process of Neodymium triacetate

There total 13 articles about Neodymium triacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

neodymium(III) oxide + acetic acid (64-19-7,77671-22-8) → neodymium(III) acetate (6192-13-8)

Guidance literature:

In acetic acid; Nd2O3 dissolved in hot acetic acid; vac. evapn. of excess acid at room temp.;

DOI:10.1016/j.jallcom.2004.03.053

Reference yield:

neodymium(III) hydroxide → neodymium(III) acetate (6192-13-8)

Guidance literature:

With H₂O; In acetic anhydride; heating under reflux for 3 hours (0.5 - hydrate) and for another 16 hours;;

DOI:10.1016/0022-1902(59)80225-6

Reference yield:

deuteroacetic acid (758-12-3) + neodymium(III) → neodymium(III) acetate (6192-13-8)

Guidance literature:

In water-d2; under N2, pH 2.0; not isolated, monitored by IR, UV, NMR;

DOI:10.1016/S0020-1693(00)85978-2

upstream raw materials:

acetic anhydride

deuteroacetic acid

acetic acid

potassium acetate

Downstream raw materials:

Nd(III) propionate

((C₆H₅)PO₂C₅H₃NCH₂)3(CH₂)6N₃Nd

silica gel

Refernces

• 1、 Prorok, Katarzyna,Pawlyta, Miros?awa,Strek, Wies?aw,Bednarkiewicz, Artur. "Energy Migration Up-conversion of Tb3+ in Yb3+ and Nd3+ Codoped Active-Core/Active-Shell Colloidal Nanoparticles". . p. 2295 - 2300. Retrieved 2016/05/10.
• 2、 Fedoseev,Budantseva,Bessonov,Shilov. "Anodic synthesis of Np(VII) compounds from acetate solutions". . p. 128 - 131. Retrieved 2012/07/14.