2-Trichlorosilylbicyclo[2.2.1]heptane

Base Information

• Chemical Name: 2-Trichlorosilylbicyclo[2.2.1]heptane
• CAS No.: 18245-29-9
• Molecular Formula: C7H11Cl3Si
• Molecular Weight: 229.609
• Hs Code.: 2931900090
• European Community (EC) Number: 242-121-3
• DSSTox Substance ID: DTXSID80885019
• Nikkaji Number: J266.074A
• Mol file: 18245-29-9.mol

Synonyms:18245-29-9;2-Trichlorosilylbicyclo[2.2.1]heptane;2-bicyclo[2.2.1]heptanyl(trichloro)silane;Silane, bicyclo[2.2.1]hept-2-yltrichloro-;EINECS 242-121-3;2-Trichlorosilylbicyclo(2.2.1)heptane;bicyclo[2.2.1]heptan-2-yltrichlorosilane;Silane, bicyclo(2.2.1)hept-2-yltrichloro-;Bicyclo(2.2.1)heptane, 2-(trichlorosilyl)-;2-(BICYCLOHEPTYL)TRICHLOROSILANE;Bicyclo(2.2.1)hept-2-yltrichlorosilane;Bicyclo[2.2.1]hept-2-yltrichlorosilane;Bicyclo[2.2.1]heptane, 2-(trichlorosilyl)-;2-(Bicycloheptyl) trichlorosilane;(5-Bicyclo[2.2.1]heptyl)trichlorosilane;3-bicyclo[2.2.1]heptanyl(trichloro)silane;C7H11Cl3Si;C7-H11-Cl3-Si;Bicycloheptyl-2-trichlorosilane;SCHEMBL1482451;endo-2-trichloro-silylnorbornane;DTXSID80885019;AKOS024334156;(Bicyclo[2.2.1]heptan-2-yl)trichlorosilane;Bicyclo[2.2.1]hept-2-yl(trichloro)silane #;(1S,4R)-bicyclo[2.2.1]hept-2-yl(trichloro)silane

Chemical Property of 2-Trichlorosilylbicyclo[2.2.1]heptane

Chemical Property:

• Vapor Pressure: 0.0537mmHg at 25°C
• Melting Point: <0 °C
• Refractive Index: 1.4919
• Boiling Point: 242.1 °C at 760 mmHg
• Flash Point: 113.1 °C
• PSA: 0.00000
• Density: 1.28 g/cm³
• LogP: 3.83190
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 227.969560
• Heavy Atom Count: 11
• Complexity: 166

Purity/Quality:

98%,99%, ^*data from raw suppliers

3-Bicyclo[2.2.1]heptanyl(trichloro)silane ^*data from reagent suppliers

Safty Information:

• Statements: 34-36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CC2CC1CC2[Si](Cl)(Cl)Cl

Technology Process of 2-Trichlorosilylbicyclo[2.2.1]heptane

There total 6 articles about 2-Trichlorosilylbicyclo[2.2.1]heptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

norborn-2-ene (498-66-8) → 2,3-bis(trichlorosilyl)bicyclo[2,2,1]heptane (620987-05-5) + 2-norbornyltrichlorosilane (18245-29-9)

Guidance literature:

With trichlorosilane; tetra-n-butylphosphonium chloride; at 180 ℃; for 12h;

Reference yield:

norborn-2-ene (498-66-8) → 2-norbornyltrichlorosilane (18245-29-9)

Guidance literature:

With trichlorosilane; dihydrogen hexachloroplatinate; at 30 - 40 ℃; for 3h;

Reference yield:

(Bicyclo<2.2.1>hept-5-en-2-yl)trichlorsilan (14319-64-3) → 2-norbornyltrichlorosilane (18245-29-9)

Guidance literature:

With hydrogen; palladium; In tetrahydrofuran; under 760 Torr;

DOI:10.1021/ja00529a074

upstream raw materials:

norborn-2-ene

(Bicyclo<2.2.1>hept-5-en-2-yl)trichlorsilan

cyclopenta-1,3-diene

Downstream raw materials:

(+/-)-endo-2-norborneol

exo-2-norbornanol

endo-2-Norbornyltrifluorosilane

exo-2-Norbornyltrifluorosilane

Refernces

• 1、 -. "Trichlorosilyl groups containing organochlorosilanes and their preparation methods by the double-silylation of olefins with trichlorosilane". Page 5. . Retrieved 2008/06/13.