Benzenepropanal, b-propyl-

Base Information

• Chemical Name: Benzenepropanal, b-propyl-
• CAS No.: 97250-26-5
• Molecular Formula: C12H16O
• Molecular Weight: 176.258
• Mol file: 97250-26-5.mol

Synonyms:

Chemical Property of Benzenepropanal, b-propyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzenepropanal, b-propyl-

There total 15 articles about Benzenepropanal, b-propyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(E)-2-Hexenal (6728-26-3) + phenylboronic acid (98-80-6) → 3-Phenylhexanal (97250-26-5)

Guidance literature:

With chloroform; palladium diacetate; caesium carbonate; triphenylphosphine; In toluene; at 80 ℃; for 16h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2008.12.032

Reference yield: 72.0%

(E)-2-Hexenal (6728-26-3) + phenyl trimethylsiloxane (2996-92-1,46143-12-8) → 3-Phenylhexanal (97250-26-5)

Guidance literature:

copper(II) bis(tetrafluoroborate); bis(dibenzylideneacetone)-palladium⁽⁰⁾; In 1,4-dioxane; water; at 95 ℃; for 23h;

DOI:10.1246/cl.2003.752

Reference yield: 70.0%

(E)-2-Hexenal (6728-26-3) + triethoxyphenylsilane (780-69-8) → 3-Phenylhexanal (97250-26-5)

Guidance literature:

With tetrabutyl ammonium fluoride; antimony(III) chloride; acetic acid; palladium diacetate; In acetonitrile; at 60 ℃; for 29h;

DOI:10.1021/jo034763r

upstream raw materials:

bromobenzene

(E)-2-Hexenal

sodium tetraphenyl borate

triphenylantimony

Refernces

• 1、 Mei, Tian-Sheng,Werner, Erik W.,Burckle, Alexander J.,Sigman, Matthew S.. "Enantioselective redox-relay oxidative heck arylations of acyclic alkenyl alcohols using boronic acids". supporting information. p. 6830 - 6833. Retrieved 2013/06/05.
• 2、 Shirakawa, Eiji,Yasuhara, Yuichi,Hayashi, Tamio. "Nickel-catalyzed conjugate addition of arylboron reagents to α,β-unsaturated carbonyl compounds with the aid of a catalytic amount of an alkyne". . p. 768 - 769. Retrieved 2007/10/03.