copper-neocuproine complex

Base Information

• Chemical Name: copper-neocuproine complex
• CAS No.: 14875-91-3
• Molecular Formula: C₂₈H₂₄CuN₄
• Molecular Weight: 480.071
• Mol file: 14875-91-3.mol

Synonyms:Copper(2+),bis(2,9-dimethyl-1,10-phenanthroline-N1,N10)-; 1,10-Phenanthroline,2,9-dimethyl-, copper complex; Bis(2,9-dimethyl-1,10-phenanthroline)copper(2+);Bis(2,9-dimethyl-1,10-phenanthroline)copper(2+) ion;Bis(2,9-dimethyl-1,10-phenanthroline)copper(II) ion;Di(2,9-dimethyl-1,10-phenanthroline)copper(2+)

Chemical Property of copper-neocuproine complex

Chemical Property:

• Vapor Pressure: 2.89E-05mmHg at 25°C
• Boiling Point: 367.4°Cat760mmHg
• Flash Point: 159.7°C
• PSA: 51.56000
• Density: g/cm³
• LogP: 6.79710

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of copper-neocuproine complex

There total 3 articles about copper-neocuproine complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(2,9-dimethyl-1,10-phenathroline) copper(I) (21710-12-3) → bis(2,9-dimethyl-1,10-phenanthroline)copper(II)(2+) (14875-91-3,50795-65-8)

Guidance literature:

With chlorine dioxide; In water; in aq. soln. at 22-25°C; Kinetics;

Reference yield:

bis(2,9-dimethyl-1,10-phenathroline) copper(I) (21710-12-3) + bis(1,4,7-triazacyclononane)nickel(III) perchlorate → bis(2,9-dimethyl-1,10-phenanthroline)copper(II)(2+) (14875-91-3,50795-65-8) + bis(1,4,7-triazacyclononane)nickel(II) perchlorate

Guidance literature:

In nitromethane; acetonitrile; (Ar); mixing of Ni(tacn)(ClO4)3 with Cu(2,9-dimethyl-1,10-phenanthroline)(1+) in 1:1 v/v mixt. of acetonitrile and nitromethane at 25°C; monitoring by UV; Kinetics;

DOI:10.1039/b415057k

Reference yield:

bis(2,9-dimethyl-1,10-phenathroline) copper(I) (21710-12-3) + bis(6,6'-dimethyl-2,2'-bipyridine)copper (II) (90316-91-9,322478-24-0) → bis(6,6'-dimethyl-2,2'-bipyridine) copper (I) (73017-53-5) + bis(2,9-dimethyl-1,10-phenanthroline)copper(II)(2+) (14875-91-3,50795-65-8)

Guidance literature:

In acetonitrile; (Ar); mixing of Cu(6,6'-dimethyl-2,2'-bipyridine))(2+) with Cu(2,9-dimethyl-1,10-phenanthroline)(1+) in MeCN at 25°C; monitoring by UV; Kinetics;

DOI:10.1039/b415057k

upstream raw materials:

bis(2,9-dimethyl-1,10-phenathroline) copper(I)

bis(6,6'-dimethyl-2,2'-bipyridine)copper (II)

Downstream raw materials:

bis(2,9-dimethyl-1,10-phenathroline) copper(I)

Refernces

• 1、 Itoh, Sumitaka,Kishikawa, Nobuyuki,Suzuki, Takayoshi,Takagi, Hideo D.. "Syntheses, structural analyses and redox kinetics of four-coordinate [CuL2]2+ and five-coordinate [CuL2(solvent)] 2+ complexes (L = 6,6′-dimethyl-2,2′-bipyridineor2,9- dimethyl-l,10-phenanthroline): Completely gated reduction reaction of [Cu(dmp)2]2+ in nitromethanet". . p. 1066 - 1078. Retrieved 2007/10/03.
• 2、 Davies, Keith M.. "Electron-transfer reactions of copper(I) and (2,9-dimethyl-1,10-phenanthroline)copper(II) with some ammine complexes of ruthenium (III) and -(II)". . p. 615 - 619. Retrieved 2008/10/08.