Iron(III)fluoride

Base Information

• Chemical Name: Iron(III)fluoride
• CAS No.: 7783-50-8
• Molecular Formula: F3Fe
• Molecular Weight: 112.842
• UNII: 0309P36Q66
• Nikkaji Number: J43.818I
• Mol file: 7783-50-8.mol

Synonyms:Iron(III)fluoride;FERRIC FLUORIDE [MI];FERRIC FLUORIDE [HSDB];A839215

Chemical Property of Iron(III)fluoride

Chemical Property:

• Appearance/Colour: green powder
• Vapor Pressure: 922mmHg at 25°C
• Melting Point: 1000 °C
• Boiling Point: 19.5 °C at 760 mmHg
• PSA: 0.00000
• Density: 3.87 g/cm³
• LogP: 1.25810
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 112.930145
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [F-].[F-].[F-].[Fe+3]

Technology Process of Iron(III)fluoride

There total 56 articles about Iron(III)fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iron(II) fluoride → iron(III) fluoride (7783-50-8) + ferric nitrate (7782-61-8)

Guidance literature:

With nitric acid; In water; discoloration of the aq. soln. of FeF2 with HNO3; formation of FeF3 and Fe(NO3)3;; pptn. as a solid mixt. on evapn.;;

Reference yield:

iron(III) fluoride trihydrate → iron(III) fluoride (7783-50-8)

Guidance literature:

In neat (no solvent); byproducts: H2O; under HF stream, 750°C;

DOI:10.1016/S0925-8388(99)00296-0

Reference yield:

hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) + iron(III) chloride (7705-08-0) → iron(III) fluoride (7783-50-8)

Guidance literature:

In neat (no solvent); decompn. with gaseous HF, formation of FeF3;;

upstream raw materials:

hydrogen fluoride

chlorine

iron

fluorine

Downstream raw materials:

(NH4)3FeF6, high temperature, cubic

Na⁽¹⁺⁾*FeF₄^(1-)=NaFeF₄

hydrogen fluoride

iron

Refernces

• 1、 Bork,Hoppe. "The first oligomeric anions of fluoro-litho metallates with octahedra sandwich motive: Cs4K{[F3MIIIF3]Li[F 3MIIIF3]}, MIII = Ga, Fe". . p. 297 - 307. Retrieved 1996.
• 2、 Gredin, Patrick,De Kozak, Ariel,Pierrard, Angelique,Calage, Yvon. "Moessbauer spectroscopy and magnetic properties of Ba5Feiii3-xMii19-x (M = Fe, Cu)". . p. 159 - 164. Retrieved 1996.
• 3、 Zhou, Xiangyang,Sun, Hongxu,Zhou, Haochen,Xu, Zhanglin,Yang, Juan. "Enhancing cycling performance of FeF3 cathode by introducing a lightweight high conductive adsorbable interlayer". . p. 317 - 326. Retrieved 2017.
• 4、 Wu, Wen,Wang, Ying,Wang, Xianyou,Chen, Quanqi,Wang, Xin,Yang, Shunyi,Liu, Xiuming,Guo, Jia,Yang, Zhenhua. "Structure and electrochemical performance of FeF3/V2O5 composite cathode material for lithium-ion battery". . p. 93 - 96. Retrieved 2009.
• 5、 Bentrup. U.,Kolditz, L.. "Synthesis and thermal decomposition of (NH4)2[MIIIF5(H2O)] (M = Al, Fe and Cr)". . p. 827 - 832. Retrieved 1988.
• 6、 Szebelledy, L.. "". . p. 165 - 165. Retrieved 1928.
• 7、 Brink, Frank J.,Withers, Ray L.,Thompson, John G.. "An electron diffraction and crystal chemical investigation of oxygen/flourine ordering in rutile-type iron oxyflouride, FeOF". . p. 359 - 365. Retrieved 2000.
• 8、 Baum, Elke,Dahlke, Patrik,Kaiser, Volker,Molinier, Michel,Schmidt, Roland E.,Pebler, Juergen,Massa, Werner,Babel, Dietrich. "On the crystal structure of pyrochlores: Moessbauer spectra of orthorhombic CsFe2F6 and X-ray single crystal studies of the cubic compounds CsMgGaF6, CsMIIVIIIF 6 (MII = Mn, Zn), CsMIIFeIIIF 6 (MII = Mn, Cu, Zn), and Cs4Cu 5V3O ...". . p. 2244 - 2250. Retrieved 2008/10/09.