Perfluorotripropylamine

Base Information

• Chemical Name: Perfluorotripropylamine
• CAS No.: 338-83-0
• Deprecated CAS: 1201928-45-1
• Molecular Formula: C9F21N
• Molecular Weight: 521.072
• Hs Code.: 2921199090
• European Community (EC) Number: 206-420-2
• UNII: 3T396UK091
• DSSTox Substance ID: DTXSID9059834
• Nikkaji Number: J191.935K
• Wikidata: Q27117994
• NCI Thesaurus Code: C166694
• ChEMBL ID: CHEMBL2104877
• Mol file: 338-83-0.mol

Synonyms:FTPA;perfluamine;perfluorotripropylamine

Chemical Property of Perfluorotripropylamine

Chemical Property:

• Appearance/Colour: colorless, odorless, clear liquid
• Vapor Pressure: 9.91mmHg at 25°C
• Melting Point: -52 °C
• Refractive Index: 1.279
• Boiling Point: 130 °C at 760 mmHg
• PKA: -27.02±0.50(Predicted)
• Flash Point: 32.4 °C
• PSA: 3.24000
• Density: 1.741 g/cm³
• LogP: 6.65960
• Storage Temp.: -20°C, Inert atmosphere
• Solubility.: DMSO (Slightly), Methanol (Slightly), Water (Slightly)
• XLogP3: 7.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 22
• Rotatable Bond Count: 6
• Exact Mass: 520.9695404
• Heavy Atom Count: 31
• Complexity: 555

Purity/Quality:

99.9% ^*data from raw suppliers

Perfluorotripropylamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(N(C(C(C(F)(F)F)(F)F)(F)F)C(C(C(F)(F)F)(F)F)(F)F)(F)F)(C(F)(F)F)(F)F
• Uses: Perfluorotripropylamine is a reagent used in the surface modification of droplet polymeric microfluidic devices. This is used to improve the stable and continueous generation of aqueous droplets.

Technology Process of Perfluorotripropylamine

There total 9 articles about Perfluorotripropylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.5%

tri-n-propylamine (102-69-2) → Perfluorotripropylamine (338-83-0)

Guidance literature:

With fluorine; sodium fluoride; In 1,1,2-Trichloro-1,2,2-trifluoroethane; at 10 ℃; for 5h;

DOI:10.1016/S0022-1139(03)00146-5

Reference yield: 2.1%

tri-n-propylamine (102-69-2) → Perfluorotripropylamine (338-83-0) + N-(F-propyl)-2-(F-ethyl)-F-pyrrolidine (97147-06-3)

Guidance literature:

With hydrogen fluoride; at 3 - 6 ℃; for 52h; electrochemical fluorination;

DOI:10.1016/S0022-1139(00)81314-7

Reference yield:

tri-n-propylamine (102-69-2) + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) → Perfluorotripropylamine (338-83-0)

Guidance literature:

In hydrogen fluoride; HF (liquid); Electrochem. Process; electrofluorination, 4-8 V, 200 A/m2, Ni anode, Fe cathode;

upstream raw materials:

tri-n-propylamine

perfluoropropylene

di-n-propylamine

Triallylamine

Refernces

• 1、 Matalin,Kaurova,Berenblit,Gribel'. "Electrochemical fluorination of toluene and benzotrifluoride in the presence of triallylamine". . p. 2090 - 2092. Retrieved 2008/09/17.
• 2、 Velayutham,Jayaraman,Noel,Krishnamoorthy,Sartori. "Cleavage path way and the product distribution pattern during the electrochemical perfluorination of tripropylamine". . p. 21 - 26. Retrieved 2007/10/03.