sodium toluene-4-thiosulphonate

Base Information

• Chemical Name: sodium toluene-4-thiosulphonate
• CAS No.: 3753-27-3
• Molecular Formula: C7H8 O2 S2 . Na
• Molecular Weight: 210.253
• Hs Code.: 2930909090
• Mol file: 3753-27-3.mol

Synonyms:Benzenesulfonothioicacid, 4-methyl-, sodium salt (9CI);p-Toluenesulfonic acid, thio-, sodium salt (7CI,8CI);Sodium 4-methylbenzenethiosulfonate;Sodium p-toluenethiosulfonate;p-Toluenethiosulfonic acid sodium salt;

Chemical Property of sodium toluene-4-thiosulphonate

Chemical Property:

• Vapor Pressure: 3.1E-05mmHg at 25°C
• Boiling Point: 341.4°Cat760mmHg
• Flash Point: 160.3°C
• PSA: 80.60000
• Density: g/cm³
• LogP: 2.74690

Purity/Quality:

99% ^*data from raw suppliers

4-METHYLBENZENESULFONOTHIOIC ACID SODIUM SALT 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of sodium toluene-4-thiosulphonate

There total 3 articles about sodium toluene-4-thiosulphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

sodium 4-methylbenzenesulfinate (824-79-3) → sodium 4-methylbenzenesulfonothioate (3753-27-3)

Guidance literature:

With sulfur; N-butylamine; at 20 ℃; for 0.5h; Other amines. In a titanium autoclave.;

DOI:10.1055/s-1980-29137

Reference yield: 86.0%

p-toluenesulfinic acid sodium salt hydrate → sodium 4-methylbenzenesulfonothioate (3753-27-3)

Guidance literature:

With sulfur; In ethanol; water; for 8h; Reflux;

DOI:10.15227/orgsyn.090.0010

Reference yield:

p-toluenesulfonyl chloride (98-59-9) → sodium 4-methylbenzenesulfonothioate (3753-27-3)

Guidance literature:

With sodium hydrogensulfide; potassium carbonate; In tetrahydrofuran; water; for 5h; Ambient temperature;

DOI:10.1016/S0223-5234(97)86179-X

upstream raw materials:

sodium 4-methylbenzenesulfinate

p-toluenesulfonyl chloride

Downstream raw materials:

1,4-bis(p-toluenesulfonylthio)butane

α,α'-Bis-p-toluolsulfonylthio-p-xylol

S,S'-ethylene bis(toluene-p-thiosulphonate)

1,3-bis(p-toluenesulfonylthio)propane

Refernces

• 1、 Musiejuk, Mateusz,Doroszuk, Justyna,J?drzejewski, Bartosz,Ortiz Nieto, Gregory,Marin Navarro, Marisol,Witt, Dariusz. "Diastereoselective Synthesis of Z-Alkenyl Disulfides from α-Thiophosphorylated Ketones and Thiosulfonates". supporting information. p. 618 - 626. Retrieved 2019/12/24.
• 2、 Doroszuk, Justyna,Musiejuk, Mateusz,Ponikiewski, ?ukasz,Witt, Dariusz. "Convenient and Efficient Diastereoselective Preparation of Functionalized Z-Alkenyl Sulfides". supporting information. p. 6333 - 6337. Retrieved 2018/11/01.