tricyclo[3.1.0.0~2,6~]hexane

Base Information

• Chemical Name: tricyclo[3.1.0.0~2,6~]hexane
• CAS No.: 287-12-7
• Molecular Formula: C6H8
• Molecular Weight: 80.1277
• Mol file: 287-12-7.mol

Synonyms:Tricyclo[2.1.1.05,6]hexane;Tricyclohexane

Chemical Property of tricyclo[3.1.0.0~2,6~]hexane

Chemical Property:

• Vapor Pressure: 102mmHg at 25°C
• Boiling Point: 78.5°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 1.169g/cm³
• LogP: 1.27220

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tricyclo[3.1.0.0~2,6~]hexane

There total 2 articles about tricyclo[3.1.0.0~2,6~]hexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

5,6-diiodobicyclo[2.1.1]hexane → Tricyclo<3.1.0.02,6>hexan (287-12-7)

Guidance literature:

With potassium cyanide; In dimethyl sulfoxide; at 20 ℃; for 4h;

DOI:10.1021/ol053039n

Reference yield:

→ tricyclo<3.1.0.02,6>hexane (287-12-7)

Guidance literature:

Δ²-Cyclopentenyldiazomethan, Photolyse, (CH3)2O;

DOI:10.1016/S0040-4039(01)89415-6

Reference yield: 96.0%

Tricyclo<3.1.0.02,6>hexan (287-12-7) → 5,6-diiodobicyclo[2.1.1]hexane

Guidance literature:

With iodine; In hexane; for 15h; Irradiation;

DOI:10.1021/ol053039n

Downstream raw materials:

(1S,4R,5S)-5-Phenylsulfanyl-bicyclo[2.1.1]hexane

Diphenyl(tricyclo<3.1.0.0^2,6>hex-1-yl)methanol

α,α'-Diphenyltricyclo<3.1.0.0^2,6>hexan-1,6-dimethanol

(E)-1,3,5-hexatriene

Refernces