Chloro(tripropyl)germane

Base Information

• Chemical Name: Chloro(tripropyl)germane
• CAS No.: 995-23-3
• Molecular Formula: C9H21ClGe
• Molecular Weight: 237.309
• DSSTox Substance ID: DTXSID40512450
• Wikidata: Q82371677
• Mol file: 995-23-3.mol

Synonyms:Chloro(tripropyl)germane;995-23-3;SCHEMBL2465364;DTXSID40512450

Chemical Property of Chloro(tripropyl)germane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 238.0543561
• Heavy Atom Count: 11
• Complexity: 76.5

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC[Ge](CCC)(CCC)Cl

Technology Process of Chloro(tripropyl)germane

There total 4 articles about Chloro(tripropyl)germane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tert-butyl 4-(tripropylgermyl)peroxybutyrate (81906-36-7) → tripropylgermane (998-27-6) + tetra-n-propylgermane (994-65-0) + dichloro(n-C3H7)2germane (19088-86-9) + tripropylchlorogermane (995-23-3) + (3-chloropropyl)tripropylgermane (81906-39-0)

Guidance literature:

With CHCl₃; In chloroform; byproducts: CO2, CH4; argon atmosphere; 135-140°C, 3 h (sealed evacuated ampul); further org. products; gas-liquid chromy.;

Reference yield:

tert-butyl 2-methyl-3-(tripropylgermyl)peroxypropionate (85273-13-8) → (C3H7)3GeCH2CH(CH3)OC(CH3)3 (85273-17-2) + tetra-n-propylgermane (994-65-0) + tripropylchlorogermane (995-23-3)

Guidance literature:

In chloroform; byproducts: CO2, CH4, (CH3)3COH; thermal decompn. in CHCl3 (75-80°C, sealed evac. ampul); furtherorg. products; gas-liquid chromy. (carrier gas helium), high-boiling residue dissoln. (ether), extn. (sodium carbonate soln.);

Reference yield:

tert-butyl 2-methyl-3-(tripropylgermyl)peroxypropionate (85273-13-8) → (C3H7)3GeCH2CH(CH3)OC(CH3)3 (85273-17-2) + (C3H7)3GeOC(O)C(CH3)CH2 (85266-42-8) + tetra-n-propylgermane (994-65-0) + tripropylchlorogermane (995-23-3)

Guidance literature:

In tetrachloromethane; byproducts: CO2, CH4, (CH3)3COH; thermal decompn. in CCl4 (75-80°C, sealed evac. ampul); further org. products; gas-liquid chromy. (carrier gas helium), high-boiling residue dissoln. (ether), extn. (sodium carbonate soln.);

upstream raw materials:

tert-butyl 4-(tripropylgermyl)peroxybutyrate

tert-butyl 2-methyl-3-(tripropylgermyl)peroxypropionate

Downstream raw materials:

dichloro(n-C₃H₇)2germane