Ir(Mppy)3 , Tris[2-(p-tolyl)pyridine]iridiuM(III)

Base Information

• Chemical Name: Ir(Mppy)3 , Tris[2-(p-tolyl)pyridine]iridiuM(III)
• CAS No.: 149005-33-4
• Molecular Formula: C₃₆H₃₀IrN₃
• Molecular Weight: 696.874
• Mol file: 149005-33-4.mol

Synonyms:Ir(Mppy)3 , Tris[2-(p-tolyl)pyridine]iridiuM(III)

Chemical Property of Ir(Mppy)3 , Tris[2-(p-tolyl)pyridine]iridiuM(III)

Chemical Property:

• PSA: 11.64000
• LogP: 7.14180
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

98% ^*data from raw suppliers

Ir(mppy)3-(OC-6-22)- 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Description: Ir(mppy)3, Tris[2-(p-tolyl)pyridine]iridium(III), is widely used as a phosphorescent dopant which emits green light in highly efficient OLED and TADF-OLED devices.?With three methyl groups attached to the ppy ligands, Ir(mppy)3?is more soluble than the widely known green emitter Ir(ppy)3.
• Uses: This versatile photocatalyst facilitates a variety of transformations using visible light.

Technology Process of Ir(Mppy)3 , Tris[2-(p-tolyl)pyridine]iridiuM(III)

There total 2 articles about Ir(Mppy)3 , Tris[2-(p-tolyl)pyridine]iridiuM(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-(4-methylphenyl)pyridine (4467-06-5) + bis(4-methyl-(2-pyridinyl-κN)phenyl-κ2C)iridium(III) chloride dimer → tris(2-phenylpyridinato)iridium(III) (149005-33-4,800394-58-5)

Guidance literature:

With K₂CO₃; In glycerol; (dark, N2); heating mixt. of iridium compd., K2CO3 and pyridine deriv. in glycerol at 150°C; Tamayo A.B., Alleyne B.D., Djurovich P.I., Lamansky S., Tsyba I., Ho N.N., Bau R., Thompson M.E., J. Am. Chem. Soc.,2003, 125, 7377-7387;

DOI:10.1021/ic800169n

Reference yield:

2-(4-methylphenyl)pyridine (4467-06-5) + [{Ir(μ-Cl)(2-(p-tolyl)pyridinato)2}2] → tris(2-phenylpyridinato)iridium(III) (149005-33-4,800394-58-5)

Guidance literature:

In glycerol; at 150 ℃;

DOI:10.1021/acs.inorgchem.6b02270

upstream raw materials:

2-(4-methylphenyl)pyridine

Refernces

• 1、 McDonald, Aidan R.,Lutz, Martin,Von Chrzanowski, Lars S.,Van Klink, Gerard P. M.,Spek, Anthony L.,Van Koten, Gerard. "Probing the mer- to fac-isomerization of tris-cyclometallated homo- and heteroleptic (C,N)3 iridium(III) complexes". . p. 6681 - 6691. Retrieved 2008.