4,4'-Diformyldiphenylamine

Base Information

• Chemical Name: 4,4'-Diformyldiphenylamine
• CAS No.: 336619-72-8
• Molecular Formula: C14H11NO2
• Molecular Weight: 225.24
• Mol file: 336619-72-8.mol

Synonyms:4,4'-Diformyldiphenylamine;Benzaldehyde, 4,4'-iminobis-

Chemical Property of 4,4'-Diformyldiphenylamine

Chemical Property:

• Boiling Point: 425.2±30.0 °C(Predicted)
• PKA: -4.70±0.40(Predicted)
• PSA: 46.17000
• Density: 1.259±0.06 g/cm3(Predicted)
• LogP: 3.12820

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4,4'-Diformyldiphenylamine

There total 2 articles about 4,4'-Diformyldiphenylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

4-[N-allyl-N-(4-formylphenyl)amino]benzaldehyde (207669-94-1) → 4-[N-(4-formylphenyl)amino]benzaldehyde (336619-72-8)

Guidance literature:

With methanesulfonic acid; palladium on activated charcoal; In ethanol; at 45 ℃;

DOI:10.1021/jo702002y

Reference yield:

4,4’-dicyanodipehnylamine (36602-05-8) → 4-[N-(4-formylphenyl)amino]benzaldehyde (336619-72-8)

Guidance literature:

With diisobutylaluminium hydride; In toluene; at 0 ℃;

DOI:10.1016/j.bmcl.2009.05.061

Reference yield:

4-[N-(4-formylphenyl)amino]benzaldehyde (336619-72-8) + C28H18BrN3 → C42H28N4O2

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In N,N-dimethyl-formamide; for 24h; Reflux; Inert atmosphere;

upstream raw materials:

4-[N-allyl-N-(4-formylphenyl)amino]benzaldehyde

4,4’-dicyanodipehnylamine

Refernces

• 1、 Lartia, Remy,Allain, Clemence,Bordeau, Guillaume,Schmidt, Falk,Fiorini-Debuisschert, Celine,Charra, Fabrice,Teulade-Fichou, Marie-Paule. "Synthetic strategies to derivatizable triphenylamines displaying high two-photon absorption". . p. 1732 - 1744. Retrieved 2008/09/18.